60029-40-5Relevant academic research and scientific papers
ARYL ADAMANTANE HAVING NITRO GROUP OR AMINO GROUP AND METHOD FOR PRODUCING THE SAME
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Paragraph 0050, (2017/10/31)
PROBLEM TO BE SOLVED: To provide aryl adamantane in which the nitro group or amino group on a phenyl group is located in the third place to an adamantane skeleton and useful as raw material for a pharmaceutical and agrochemical intermediate, a functional
Ruthenium-catalyzed meta/ortho-selective C-H alkylation of azoarenes using alkyl bromides
Li, Gang,Ma, Xingxing,Jia, Chunqi,Han, Qingqing,Wang, Ya,Wang, Junjie,Yu, Liuyang,Yang, Suling
, p. 1261 - 1264 (2017/02/05)
meta/ortho-Selective CAr-H (di)alkylation reactions of azoarenes have been achieved via [Ru(p-cymene)Cl2]2 catalyzed ortho-metalation using various types of alkyl bromides. Particularly, dual meta-alkylation of azoarene and reduction offer an attractive strategy for the synthesis of meta-alkylanilines, which are difficult to access via traditional aniline functionalization methods.
REACTION OF 1-HYDROXYADAMANTANE WITH AROMATIC AMINES IN THE PRESENCE OF ORTHO-ALKYLATION CATALYSTS
Olifirov, D. I.,Koshchii, V. A.,Kozlikovskii, Ya. B.
, p. 152 - 157 (2007/10/02)
The reaction of 1-hydroxyadamantane with aniline and N-methylaniline in the presence of hydrochlorides of the corresponding amines and aluminum anilide gives a mixture of mono- and di(1-adamantyl)anilines and 4,4'-di(1-adamantyl)diphenylamine, in which th
