60048-13-7 Usage
General Description
(Triphenylstannanyl)acetonitrile is a chemical compound that consists of a triphenylstannyl group attached to an acetonitrile molecule. It is often used as a reagent in organic synthesis reactions. The triphenylstannyl group serves as a source of a phenyl group, while the acetonitrile molecule can act as a nucleophile or a source of a cyano group in various reactions. (triphenylstannanyl)acetonitrile is used in cross-coupling reactions to form carbon-carbon and carbon-heteroatom bonds, as well as in the synthesis of complex organic molecules. Additionally, (triphenylstannanyl)acetonitrile can be used as a precursor for the preparation of other functionalized stannanes or organotin compounds. Due to the presence of the stannyl group, this compound should be handled with care, as organotin compounds can be toxic and harmful to the environment.
Check Digit Verification of cas no
The CAS Registry Mumber 60048-13-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,0,0,4 and 8 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 60048-13:
(7*6)+(6*0)+(5*0)+(4*4)+(3*8)+(2*1)+(1*3)=87
87 % 10 = 7
So 60048-13-7 is a valid CAS Registry Number.
60048-13-7Relevant articles and documents
Homologation of halostannanes with carbenoids: a convenient and straightforward one-step access to α-functionalized organotin reagents
Touqeer, Saad,Castoldi, Laura,Langer, Thierry,Holzer, Wolfgang,Pace, Vittorio
supporting information, p. 10112 - 10115 (2018/09/13)
A direct, single synthetic homologative transformation of halostannanes into mono- or di-substituted methyl analogues is documented. Critical for the success of the operation is the excellent nucleophilicity of carbenoid-like methyllithium reagents (LiCHXY, X, Y = halogen, OR, and CN): by simply individuating the reagents' substitution pattern, the desired functionalized fragment is delivered to the electrophile. The wide scope of the protocol is evidenced also in the case of analogous halogermanium compounds. The tandem homologation-quenching with nucleophiles and the use of α-chloroallyllithium is also discussed.
