6005-75-0

Basic information

• Product Name: N-[2-(4-methoxyphenyl)ethyl]-4-methyl-3-nitrobenzamide
• Synonyms: benzamide, N-[2-(4-methoxyphenyl)ethyl]-4-methyl-3-nitro-
• CAS NO: 6005-75-0
• Molecular Formula: C₁₂H₁₄O
• Molecular Weight: 314.3358
• Mol File: 6005-75-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 496.3°C at 760 mmHg
• Flash Point: 253.9°C
• Density: 1.213g/cm³
• Vapor Pressure: 5.49E-10mmHg at 25°C
• Refractive Index: 1.586
• CAS DataBase Reference: N-[2-(4-methoxyphenyl)ethyl]-4-methyl-3-nitrobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[2-(4-methoxyphenyl)ethyl]-4-methyl-3-nitrobenzamide(6005-75-0)
• EPA Substance Registry System: N-[2-(4-methoxyphenyl)ethyl]-4-methyl-3-nitrobenzamide(6005-75-0)

Safety Data

• Hazardous Substances Data: 6005-75-0(Hazardous Substances Data)

Upstream product

• 27064-03-5 S-phenyl methanethioate 
• 855234-98-9 2-ethyl-1-phenyl-but-3-ene-1,2-diol 

Downstream Products

• 172472-72-9 N-(benzylidene)-2-ethyl-2-phenyl-3-butenylamine 

Relevant articles and documents

Transition-Metal-Free Formylation of Allylzinc Reagents Leading to α-Quaternary Aldehydes

The first example of formylation of allylzinc reagents using S-phenyl thioformate is presented. The reaction proceeded under mild conditions without any transition-metal catalyst, forming quaternary carbon centers with reactive functionalities, such as formyl and vinyl groups. Moreover, Barbier-type formylation of an allylic bromide with a sterically demanding thioformate was achieved. As a preliminary result, asymmetric formylation was conducted using a menthol-derived chiral thioformate.