60053-29-4Relevant academic research and scientific papers
Copper(I)-catalyzed stereoselective defluoroborylation of aliphatic gem-difluoroalkenes
Ito, Hajime,Seo, Tamae,Kojima, Ryoto,Kubota, Koji
, p. 1330 - 1332 (2018)
This study reports a method for the stereoselective copper(I)catalyzed defluoroborylation of aliphatic gem-difluoroalkenes to afford (Z)-monofluoro-substituted borylalkenes. Gem-difluoro-alkenes bearing a variety of functional groups were efficiently borylated with high stereoselectivity. A theoretical study of the reaction mechanism is also described.
