60066-50-4Relevant academic research and scientific papers
Reactions of vinylcyclopropane epoxides with samarium and phosphorus iodides
Krief, Alain,Dumont, Willy,Baillieul, Diane
, p. 2688 - 2690 (2005)
Samarium diiodide on one hand, diphosphorus tetraiodide, and phosphorus triiodide on the other, react with vinylcyclopropane epoxides to produce either allylic alcohols or vinylcyclopropanes resulting from cyclopropane ring-opening or deoxygenation of the epoxide, respectively. Georg Thieme Verlag Stuttgart.
Process for preparing dihalovinylcyclopropanecarboxylates
-
, (2008/06/13)
Novel syntheses of dihalovinylcyclopropanecarboxylates, including potent insecticides, are described. The processes begin with the reaction between an alkenol and an orthoester to produce a γ-unsaturated carboxylate, followed by the catalyzed addition of a carbon tetrahalide to the double bond and dehydrohalogenation to produce a cyclopropane derivative.
