60067-95-0

Upstream product

• 504-02-9 1,3-cylohexanedione 
• 23074-59-1 3-isobutoxycyclohex-2-en-1-one 
• 74-88-4 methyl iodide 

Downstream Products

• 108579-41-5 (3-Butyl-3-isobutoxy-6-methyl-cyclohex-1-enyloxy)-trimethyl-silane 
• 108579-42-6 (1-Butyl-3-isobutoxy-6-methyl-cyclohex-2-enyloxy)-trimethyl-silane 
• 81465-48-7 3-Iodo-4-methyl-cyclohex-2-enone 
• 81465-40-9 3-iodo-6-methyl-2-cyclohexen-1-one 
• 81465-54-5 3-Iodo-4-methyl-cyclohex-3-enone 
• 290839-11-1 4-methyl-3-phenyl-4-(3-oxobutyl)cyclohex-2-en-1-one 
• 290839-10-0 3-butyl-4-methyl-4-(3-oxobutyl)cyclohex-2-en-1-one 
• 290839-09-7 3,4-dimethyl-4-(3-oxobutyl)cyclohex-2-en-1-one 
• 5259-53-0 4-methyl-4-(3-oxobutyl)cyclohex-2-en-1-one 
• 375384-96-6 6-((Z)-4-benzyloxy-3-iodobut-2-en-1-yl)-3-isobutoxy-6-methylcyclohex-2-en-1-one 
• 375384-92-2 6-((Z)-3-iodobut-2-en-1-yl)-3-isobutoxy-6-methylcyclohex-2-en-1-one 
• 60067-97-2 3-isobutyloxy-6,6-dimethylcyclohex-2-en-1-one 
• 14203-46-4 4-methyl-cyclohexane-1,3-dione 
• 375385-05-0 4-((Z)-4-benzyloxy-3-iodobut-2-en-1-yl)-4-methylcyclohex-2-en-1-one 

Relevant academic research and scientific papers

Aldol condensation versus conjugate addition: Intramolecular cyclization using a combination of Lewis acid and 1,2-diol

The reactivity of 3-substituted 4-methyl-4-(3-oxobutyl)-2-cyclohexen-1-ones (1) in the presence of a combination of a Lewis acid and a 1,2-diol was studied. The results suggest several factors that influence 6-membered ring formation, including two types of intramolecular aldol reaction and intramolecular 1,4-addition, due to the C3-substituent, Lewis acid, and the presence of diol. In this study, novel methodology to prepare two types of decalin skeleton could be developed.

Synthesis of β-chloro, β-bromo, and β-iodo α,β-unsaturated ketones

A new, efficient method for the preparation of β-chloro, β-bromo, and β-iodo α,β-unsaturated ketones is described.The method involves the reaction of β-diketones or α-hydroxymethylenecycloalkanones with triphenylphosphine dihalides in the presence of trie