60072-22-2Relevant academic research and scientific papers
Diversity-oriented synthesis of hydrazine-derived compounds from amino isocyanates generated in situ
Clavette, Christian,Vincent Rocan, Jean-Francois,Beauchemin, Andre M.
, p. 12705 - 12708 (2013)
Behind the mask: Nitrogen-substituted isocyanates are rare and their synthetic potential is virtually untapped. Simple masked precursors can form amphoteric amino isocyanate intermediates in situ, and allows the synthesis of complex hydrazine derivatives upon addition with amines. This reactivity was used in a cascade substitution/hydroamination sequence, and in the assembly of azadipeptide analogues. Copyright
PROCESS FOR THE SYNTHESIS OF BETA-AMINOCARBONYLS
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Page/Page column 00395, (2013/05/23)
The present application provides processes and intermediates useful in the production of β- aminocarbonyl- or β-aminothiocarbonyl-containing compounds. Provided herein is a process for synthesizing β-aminocarbonyl- or β-aminothiocarbonyl-containing compounds from an alkene and a hydrazone. Also provided herein is a process for synthesizing β-aminocarbonyl- or β-aminothiocarbonyl-containing compounds from an alkene and a hydrazine. The present application further provides intermediate aminoisocyanate and iminoisocyanate compounds, and methods for synthesizing the starting hydrazone and hydrazine compounds.
