60079-98-3Relevant academic research and scientific papers
Visible-light-catalyzed arylboronic-acid phenol preparation method
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Paragraph 0009; 0025, (2017/06/02)
The invention discloses a visible-light-catalyzed arylboronic-acid phenol preparation method, and belongs to the technical field of organic synthesis. According to the preparing method, and under the conditions of the room temperature, air, visible light and amine, an iridium complex or a platinum complex serves as a catalyst, and arylboronic acid is subjected to an oxidation hydroxylation reaction, and a phenol compound is generated. According to the method, oxygen in the air serves as an oxidizing agent, and the method has the advantages of being good in atom economy, mild in reaction condition, easy and convenient to operate and the like; the synthetic method of the phenol compound is enriched, and particularly, a simple, convenient and efficient method is provided for synthesis of a large-conjugation phenol compound.
