60092-82-2Relevant academic research and scientific papers
Facile synthesis of sulfonyl amidines by 1,3-dipolar cycloaddition between 1-morpholinocycloalkenes and sulfonyl azides without catalyst
Adiche, Chiaa,Hamadouche, Mohammed,Abed, Douniazad El
, p. 1614 - 1628 (2016)
Three new series of sulfonyl amidines were prepared by 1,3-dipolar cycloaddition reaction between 1-morpholinocycloalkenes and various substituted sulfonyl azides without catalyst at room temperature. This reaction yielded unstable bicyclic Δ2 -1,2,3- Triazoline intermediates which rearranged themselves in situ into amidines by elimination of a nitrogen molecule. The reactions were performed under mild conditions and with moderate to good yields.
