60101-93-1

Upstream product

• 366-18-7 [2,2]bipyridinyl 

Downstream Products

• 212497-84-2 [Pd(C6F5)(bipy)(μ-SC6F5)Pt(C6F5)(dppe)]CF3SO3 
• 212497-68-2 [Pd(C6F5)(bipy)(μ-SC6F5)Pd(C6F5)(dppe)]CF3SO3 
• 212497-65-9 [Pd(C6F5)(bipy)(μ-SC6F5)Pd(C6F5)(phen)]CF3SO3 
• 212497-80-8 [Pd(C6F5)(bipy)(μ-SC6F5)Pt(C6F5)(bipy)]CF3SO3 
• 212497-62-6 [Pd(C6F5)(bipy)(μ-SC6F5)Pd(C6F5)(bipy)]CF3SO3 
• 212497-45-5 Pd(SC₆F₅)(C₆F₅)(C₁₀H₈N₂) 
• 90160-78-4 (μ-Br)[Pd(C6F5)(2,2'-bipyridine)]2ClO4 
• 90143-66-1 Pd(P(C₆H₅)3)(C₁₀H₈N₂)(C₆F₅)⁽¹⁺⁾*ClO₄^(1-)=[Pd(P(C₆H₅)3)(C₁₀H₈N₂)(C₆F₅)](ClO₄) 
• 90143-64-9 (μ-Cl)[Pd(C6F5)(2,2'-bipyridine)]2ClO4 
• 90143-62-7 (μ-SCN)[Pd(C6F5)(2,2'-bipyridine)]2ClO4 
• 90143-60-5 (μ-CN)[Pd(C6F5)(2,2'-bipyridine)]2ClO4 
• 90143-75-2 [Pd(SCN)(C₆H₅)(2,2'-bipyridine)] 
• 90143-74-1 [Pd(CN)(C₆H₅)(2,2'-bipyridine)] 
• 1029116-88-8 [Pd(2,2'-bipyridine)(C₆F₅)(4,7-dihydro-5-methyl-7-oxo[1,2,4]triazolo[1,5-a]pyrimidine)]ClO₄ 

Relevant academic research and scientific papers

Synthesis of Cationic Palladium(II) and Platinum(II) Complexes with a Monodentate Trialkylphosphoniumditiocarboxylate Ligand: Molecular Structure of trans-ClO4*CHCl3

Reaction of trans- with the zwitterion S2C-PR'3 affords the complexes trans-ClO4 (M= Pd; R3=R'3= Et3, Bu3 or Et2Ph; R= Bu, R'= cyclo-C6H11; R= Ph, R'= Et or cyclo-C6H11; M= Pt, R=R'= Et or Bu). trans-ClO4 is also given by reaction of ClO4 with CS2.Reaction of (bipy= 2,2'-bipyridyl) with S2C-PR'3 affords ClO4 (M=Pd or Pt; R'=Et, Bu, or cyclo-C6A11).A crystallographic study of trans-ClO4 (as its 1:1 chloroform solvate) shows that the cation contains a unidentate triethylphosphoniumdithiocarboxylate ligand, and 31P n.m.r. spectra of all products with two terminal phosphine ligands are consistent with trans stereochemistries.Crystals of trans-ClO4*CHCl3 are monoclinic, space group P21/a, with a=14.596 5(18), b=15.356(3), c=19.324 2(16) angstroem, β=109.257(8) deg, and Z=4.Using 4 093 amplitudes the structure has been refined to R=0.1049.The non-bonding Pd...S distance is 3.644(4) angstroem.