60144-60-7Relevant academic research and scientific papers
1,3-Dithiane-derived alkoxyamines as one-carbon radical precursors
Herrera, Antonio J.,Studer, Armido
, p. 1389 - 1396 (2005)
A new method for the generation of C-2 centered radicals derived from 1,3-dithiane is presented. The radical precursors, 2-dialkylaminoxyl-1,3- dithianes, are readily prepared from 1,3-dithiane and stable nitroxides. Thermal reaction of 2-dialkylaminoxyl-1,3-dithianes with electron-deficient olefins affords carboaminoxylation products oroxidative addition products depending on the nitroxide used. The 2-dialkylaminoxyl-1,3-dithianes can also be used as initiators/regulators for the controlled living free radical polymerization of styrene. Georg Thieme Verlag Stuttgart.
