60205-12-1

Upstream product

• 1520080-26-5 (E)-isopropyl methyl(2-methylbut-2-en-1-yl)carbamate 
• 497-03-0 2-methylbut-2-enal 
• 1333163-97-5 (E)-N,2-dimethylbut-2-en-1-amine 
• 84483-80-7 2-bromo-5-(trichloroacetyl)-1,3,4-trimethylpyrrole 
• 84483-79-4 2-(trichloroacetyl)-1,3,4-trimethylpyrrole 
• 30144-12-8 1,3,4-trimethyl-pyrrole 
• 822-51-5 3,4-dimethyl-1H-pyrrole 

Downstream Products

• 85870-82-2 E-1,3,4-trimethyl-5-(phenylmethylidene)-3-pyrrolin-2-one 
• 85870-81-1 Z-1,3,4-trimethyl-5-(phenylmethylidene)-3-pyrrolin-2-one 
• 85870-84-4 E-1,3,4-trimethyl-5-(4-methoxyphenylmethylidene)-3-pyrrolin-2-one 
• 85870-83-3 Z-1,3,4-trimethyl-5-(4-methoxyphenylmethylidene)-3-pyrrolin-2-one 

Relevant academic research and scientific papers

Smooth isoindolinone formation from isopropyl carbamates via bischler-napieralski-type cyclization

Isopropyl carbamates derived from benzylamines provide isoindolinones by treatment with phosphorus pentoxide at room temperature. Utility of this Bischler-Napieralski-type cyclization and a new mechanism involving a carbamoyl cation for rationalization of this smooth conversion are discussed.

1,3,4-Trimethyl-2,2'-pyrromethen-5-one and its 1'-methyl derivative; Synthesis, and thermal and photochemical reactivity

Condensation of 1,3,4-trimethyl-1,5-dihydro-2H-pyrrol-2-one, prepared in high yield from 3,4-dimethylpyrrole, with pyrrole-2-carboxaldehyde and 1-methylpyrrole-2-carboxaldehyde gives a mixture of Z- and E-1,3,4-trimethyl-2,2'-pyrromethen-5-one (7 and