602278-90-0

Basic information

• Product Name: D-3,6-di-O-[(S)-O-acetylmandeloyl]-1,2-O-isopropylidene-myo-inositol
• Synonyms: D-3,6-di-O-[(S)-O-acetylmandeloyl]-1,2-O-isopropylidene-myo-inositol
• CAS NO: 602278-90-0
• Molecular Weight: 572.566
• Mol File: 602278-90-0.mol

Chemical Properties

• CAS DataBase Reference: D-3,6-di-O-[(S)-O-acetylmandeloyl]-1,2-O-isopropylidene-myo-inositol(CAS DataBase Reference)
• NIST Chemistry Reference: D-3,6-di-O-[(S)-O-acetylmandeloyl]-1,2-O-isopropylidene-myo-inositol(602278-90-0)
• EPA Substance Registry System: D-3,6-di-O-[(S)-O-acetylmandeloyl]-1,2-O-isopropylidene-myo-inositol(602278-90-0)

Safety Data

• Hazardous Substances Data: 602278-90-0(Hazardous Substances Data)

Upstream product

• 51548-88-0 (+/-)-1,2:4,5-di-O-isopropylidene-myo-inositol 
• 51019-44-4 (S)-2-chloro-2-oxo-1-phenylethyl acetate 
• 7322-88-5 (S)-acetylmandelic acid 
• 6404-82-6 (+/-)-1,2-O-isopropylidene-myo-inositol 
• 191488-25-2 D-3,6-di-O-[(S)-O-acetylmandeloyl]-1,2:4,5-di-O-isopropylidene-myo-inositol 

Relevant articles and documents

Resolution of synthetically useful myo-inositol derivatives using the chiral auxiliary O-acetylmandelic acid

Efficient methods for the resolution of various myo-inositol derivatives have been developed using O-acetylmandelic acid (OAM) as the chiral auxiliary. Various methods of introduction of the chiral auxiliary have been compared. DCC mediated coupling betwe

A simple and practical resolution of 1,2:4,5-di-O-isopropylidene-myo-inositol

An efficient method for the resolution of 1,2:4,5-di-O-isopropylidene-myo-inositol has been developed. The diketal was converted to diastereomeric 3,6-di-O-mandelates by the reaction with (S)-O-acetylmandeloyl chloride. Both the diastereomers could be separated by sequential crystallization in multi-gram quantities. The enantiomers of the diol were obtained by removal of the chiral auxiliaries. Also the trans-isopropylidene was cleaved efficiently to obtain another pair of chiral diols.