602304-99-4Relevant academic research and scientific papers
Fluoride-induced chemiluminescent decomposition of dioxetanes bearing a siloxyaryl moiety to produce an alkyl aryl ketone as an emitter
Watanabe, Nobuko,Nagashima, Yasuhiro,Yamazaki, Takahiro,Matsumoto, Masakatsu
, p. 4811 - 4819 (2007/10/03)
Tetrabutylammonium fluoride induces the decomposition of 1-tert-butyl-4,4-dimethyl-5-(3-siloxyphenyl)-2,6,7-trioxabicyclo[3.2.0] heptane (4a) in DMSO to form an oxyanion of aromatic ketone (14a) as an emitter with high singlet-chemiexcitation yield comparable with that for a chemically initiated electron exchange luminescence (CIEEL) active dioxetane producing an oxyanion of aromatic ester as an emitter. A 7-siloxynaphthalen-2-yl analog (4b) was found on similar treatment to emit light with the maximum wavelength the longest among CIEEL-active dioxetanes hitherto known.
