60236-80-8

Basic information

• Product Name: Benzoyl azide, 4-cyano-
• CAS NO: 60236-80-8
• Molecular Formula: C8H4N4O
• Molecular Weight: 172.146
• Mol File: 60236-80-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzoyl azide, 4-cyano-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl azide, 4-cyano-(60236-80-8)
• EPA Substance Registry System: Benzoyl azide, 4-cyano-(60236-80-8)

Safety Data

• Hazardous Substances Data: 60236-80-8(Hazardous Substances Data)

Upstream product

• 619-65-8 4-cyanobenzoic Acid 
• 50-00-0 formaldehyd 
• 3058-39-7 4-iodobenzonitrile 
• 201230-82-2 carbon monoxide 
• 32792-64-6 2,4-dinitrophenyl 4-cyanobenzoate 
• 6068-72-0 4-cyanobenzoyl chlorIde 

Downstream Products

• 86065-51-2 1-(4-cyanophenyl)urea 
• 1372868-22-8 4-cyano-N-(phenylcarbamoyl)benzamide 
• 873-74-5 4-Aminobenzonitrile 
• 17922-99-5 N-benzyl-p-cyanobenzamide 
• 40465-45-0 p-cyanophenyl isocyanate 
• 17923-00-1 N-(4-cyanophenyl)-2-phenylpropanamide 

Relevant articles and documents

Synthesis of Acyl Phosphoramidates Employing a Modified Staudinger Reaction

A one-step synthesis of acyl phosphoramidates from a variety of functionalized acyl azides has been developed employing trimethylsilyl chloride as an activating agent in a modified Staudinger reaction. The methodology was further adapted to include the in situ generation of the acyl azides from a diverse selection of carboxylic acids and hydrazide starting synthons. The reaction scope was extended to include the synthesis of imidodiphosphates and the natural product Microcin C.

Synthesis of Acyl Azides from 1,3-Diketones via Oxidative Cleavage of Two C-C Bonds

A metal-free PhI(OAc)2-mediated method for the synthesis of acyl azides through oxidative cleavage of 1,3-diketones is described. This method is shown to have a broad substrate scope, providing a useful tool for multiproduct synthesis in a single procedure. A possible reaction pathway is proposed based on mechanistic studies.

Iridium(III)-Catalyzed Selective and Mild C-H Amidation of Cyclic N-Sulfonyl Ketimines with Organic Azides

A general protocol for iridium catalyzed direct C?H amidation of cyclic N-sulfonyl ketimines using sulfonyl, acyl and aryl azides as nitrogen source is reported herein. The reaction takes place at room temperature with acyl and aryl azides, while an elevated temperature needed with sulfonyl azides to furnish aminated sultams in excellent yields with complete chemo and regioselectivity, thus providing a robust and environmentally benign process to the synthesis of aminosultams. (Figure presented.).