6026-08-0Relevant articles and documents
Regioselective alkylation of 1-silyl-2-methylallyl carbanions
Li,Wang d.
, p. 2879 - 2882 (2007/10/02)
Regioselective alkylations of 1-silyl-2-methylallyl carbanions were achieved by changing the substituents on silicon. γ-Alkylation was favoured by dialkylamino group on silicon, whereas α-alkylation was favoured by an alkoxy substituent on silicon.
Metalated Allylaminosilane: A New, Practical Reagent for the Stereoselective α-Hydroxyallylation of Aldehydes to Erythro-1,2-diol Skeletons
Tamao, Kohei,Nakajo, Eiji,Ito, Yoshihiko
, p. 957 - 958 (2007/10/02)
A zinc reagent derived from allyl(diisopropylamino)dimethylsilane reacts with aldehydes regio- and stereoselectively to form erythro-3-silyl-1-alken-4-ols, which are further transformed into erythro-1-alkene-3,4-diols by hydrogen peroxide oxidation of the