Welcome to LookChem.com Sign In|Join Free

CAS

  • or

603-36-1

Post Buying Request

603-36-1 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • Triphenylantimony CAS 603-36-1 Stibine, triphenyl- CAS no 603-36-1 Triphenylstibine Triphenylantimony(III)

    Cas No: 603-36-1

  • USD $ 3.5-5.0 / Kiloliter

  • 5 Kiloliter

  • 3000 Metric Ton/Month

  • Chemwill Asia Co., Ltd.
  • Contact Supplier

603-36-1 Usage

Chemical Properties

off-white powder

Uses

Stibonium salts, cocatalyst in converting trienes to aromatics and hydroaromatics, react with nitricsulfuric acid to give trinitro derivatives, polymerization inhibitor, lubricating-oil additive.

General Description

Atomic number of base material: 51 Antimony

Safety Profile

Poison by ingestion and intraperitoneal routes. Flammable when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use water, foam, mist. When heated to decomposition it emits toxic fumes of Sb. See also ANTIMONY COMPOUNDS.

Purification Methods

Recrystallise Ph3Sb from acetonitrile [Hayes et al. J Am Chem Soc 107 1346 1985]. [Beilstein 16 H 891, 16 IV 1198.]

Check Digit Verification of cas no

The CAS Registry Mumber 603-36-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,0 and 3 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 603-36:
(5*6)+(4*0)+(3*3)+(2*3)+(1*6)=51
51 % 10 = 1
So 603-36-1 is a valid CAS Registry Number.
InChI:InChI=1/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H;/rC18H15Sb/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

603-36-1 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Sigma-Aldrich

  • (92940)  Triphenylantimony(III)  purum, ≥99.0% (HPLC)

  • 603-36-1

  • 92940-100G

  • 1,098.63CNY

  • Detail
  • Aldrich

  • (T81809)  Triphenylantimony(III)  99%

  • 603-36-1

  • T81809-25G

  • 396.63CNY

  • Detail
  • Aldrich

  • (T81809)  Triphenylantimony(III)  99%

  • 603-36-1

  • T81809-100G

  • 954.72CNY

  • Detail

603-36-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Triphenylantimony

1.2 Other means of identification

Product number -
Other names triphenylstibane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:603-36-1 SDS

603-36-1Synthetic route

tetraphenyl stibonium iodide
13903-91-8, 16894-70-5

tetraphenyl stibonium iodide

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In water Electrochem. Process; reduction;100%
diphenylfluorostibine
6651-55-4

diphenylfluorostibine

phenyltrifluorosilane
368-47-8

phenyltrifluorosilane

A

triphenylantimony
603-36-1

triphenylantimony

B

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
reflux for 3 d;A 100%
B n/a
reflux for 3 d;A 100%
B n/a
vanadocene

vanadocene

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

vanadocene monochloride

vanadocene monochloride

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene a soln. of vanadocene and dichlorotriphenylantimony (2:1) in toluene at room temp. for 20 h, mixt. becomes blue; solvent is removed in vac., triphenylstibine is extd. with hexane, residue consists of dark blue crystals; elem. anal.;A 98%
B 99%
vanadocene

vanadocene

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

bis(cyclopentadienyl)vanadium dichloride
12083-48-6

bis(cyclopentadienyl)vanadium dichloride

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene heating of vanadocene and dichlorotriphenylantimony in the ratio of 1:1 in toluene at 100°C for 5 h;; removal of solvent under vac.; the stibine was extd. with hexane;;A n/a
B 99%
NiOs3H3(1+)*C5H5(1-)*8CO*Sb(C6H5)3=(C5H5)NiOs3H3(CO)8(Sb(C6H5)3)

NiOs3H3(1+)*C5H5(1-)*8CO*Sb(C6H5)3=(C5H5)NiOs3H3(CO)8(Sb(C6H5)3)

triphenylphosphine
603-35-0

triphenylphosphine

A

NiOs3H3(1+)*C5H5(1-)*8CO*P(C6H5)3=(C5H5)NiOs3H3(CO)8(P(C6H5)3)

NiOs3H3(1+)*C5H5(1-)*8CO*P(C6H5)3=(C5H5)NiOs3H3(CO)8(P(C6H5)3)

B

NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

C

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In hexane The complex and a slight excess of Pp are refluxed in hexane for 5 min (N2). Some decompn. was observed.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;A 99%
B n/a
C n/a
(C6H5)4SbSC6H5*0.06CHCl3

(C6H5)4SbSC6H5*0.06CHCl3

A

biphenyl
92-52-4

biphenyl

B

diphenyl sulfide
139-66-2

diphenyl sulfide

C

triphenylantimony
603-36-1

triphenylantimony

D

diphenyldisulfane
882-33-7

diphenyldisulfane

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 21%
B 69%
C 99%
D 30%
E 6%
antimony(III) chloride
10025-91-9

antimony(III) chloride

chlorobenzene
108-90-7

chlorobenzene

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
Stage #1: chlorobenzene With cis-Octadecenoic acid; sodium In toluene at 30 - 40℃; for 2h; Inert atmosphere;
Stage #2: antimony(III) chloride In toluene at 110℃; for 3.5h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere;
98.1%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

H3COC6H4SCCl3

H3COC6H4SCCl3

C

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

D

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In tetrachloromethane Kinetics; at 34°C; not isolated, GLC;A 47%
B 5%
C 48%
D 98%
In chloroform-d1 Kinetics; at 34°C; not isolated, GLC;A 35%
B 5%
C 64%
D 95%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

biphenyl
92-52-4

biphenyl

C

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

D

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In neat (no solvent) 130°C; not isolated, GLC;A 69%
B 17%
C 28%
D 98%
In cyclohexene reflux; not isolated, GLC;A 80%
B 12%
C 18%
D 98%
In benzene reflux; not isolated, GLC;A 86%
B 4%
C 8%
D 95%
In chloroform reflux; not isolated, GLC;A 70%
B 4%
C 19%
D 95%
(C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4SbSC6H4OCH3*0.11CHCl3

A

biphenyl
92-52-4

biphenyl

B

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

C

1-methoxy-4-(phenylsulfanyl)benzene
5633-57-8

1-methoxy-4-(phenylsulfanyl)benzene

D

triphenylantimony
603-36-1

triphenylantimony

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 17%
B 28%
C 69%
D 98%
E 13%
triphenylantimony bis(2,4-dimethylbenzenesulfonate)

triphenylantimony bis(2,4-dimethylbenzenesulfonate)

A

zinc bis(2,4-dimethylbenzenesulfonate)

zinc bis(2,4-dimethylbenzenesulfonate)

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In acetone Sb comp. and Zn dust heated in acetone in a sealed glass ampule at 90°C for 2 h; solvent removed, residue treated with hexane and then with alcohol; products detected by IR spectra;A 98%
B 95%
antimony(III) chloride
10025-91-9

antimony(III) chloride

lithium
7439-93-2

lithium

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
With bromobenzene In diethyl ether with 20% excess of Li at 0°C then reflux for 2 h;97%
(2,6-dimethylphenoxy)tetraphenylantimony
209054-80-8

(2,6-dimethylphenoxy)tetraphenylantimony

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In neat (no solvent) byproducts: 2,6,2',6'-tetramethyldiphenoquinone; heated for 1 h at 220°C in a glass evacuated ampoule; sepd. by chromy. on silica gel; eluted with petroleum ether;97%
cobaltocene
1277-43-6

cobaltocene

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

cobalticenium chloride

cobalticenium chloride

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene a mixt. of cobaltocene and dichlorotriphenylstibine in toluene is heated at 100°C for 3 h, decolorization of soln. and formation of a light-green ppt. is observed,; ppt. is extd. with toluene and toluene is driven off to give triphenylstibine, the residual light-green powder is chlorodicyclopentadienylcobalt;A 96%
B 97%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

C

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In benzene-d6 reflux; not isolated, GLC;A 86%
B 7%
C 97%
(C6H5)4SbSC6H4OCH3*0.5CHCl3

(C6H5)4SbSC6H4OCH3*0.5CHCl3

A

biphenyl
92-52-4

biphenyl

B

bis(2-methoxyphenyl)disulfide
13920-94-0

bis(2-methoxyphenyl)disulfide

C

1-methoxy-2-(phenylthio)benzene
14065-22-6

1-methoxy-2-(phenylthio)benzene

D

triphenylantimony
603-36-1

triphenylantimony

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 6%
B 5%
C 92%
D 97%
E 4%
(C6H5)4SbSC6H4Br*0.12CHCl3

(C6H5)4SbSC6H4Br*0.12CHCl3

A

biphenyl
92-52-4

biphenyl

B

bis(4-bromophenyl)disulfide
5335-84-2

bis(4-bromophenyl)disulfide

C

phenyl(4-bromophenyl)sulfide
65662-88-6

phenyl(4-bromophenyl)sulfide

D

triphenylantimony
603-36-1

triphenylantimony

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 3%
B 3%
C 97%
D 96%
E 3%
(3,5-di-tert-butylphenoxy)tetraphenylantimony
329747-31-1

(3,5-di-tert-butylphenoxy)tetraphenylantimony

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In neat (no solvent) byproducts: PhOC6H3(tert-bu)2; heating for 1 h at 220°C in a glass evacuated ampoule; recrystd. from EtOH;97%
bromobenzene
108-86-1

bromobenzene

antimony(III) chloride
10025-91-9

antimony(III) chloride

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
Stage #1: bromobenzene With sodium; stearic acid In toluene at 40℃; for 1h; Inert atmosphere;
Stage #2: antimony(III) chloride In toluene at 110℃; for 3.5h; Solvent; Reagent/catalyst; Inert atmosphere;
96.5%
2-aminotropone
6264-93-3

2-aminotropone

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
With potassium tert-butylate; 2-hydroxy-2-phenylacetophenone In benzene byproducts: benzil; under N2; t-BuOK added to stirred soln. of Ph3SbCl2 and H2NC7H5O (molar ratio 2:1:1) in dry benzene; stirred at room temp. for 30 min; benzoin (1 equiv.) added; heated under reflux for 1.5 h; solvent evapd.; sepd. by column chromy. (SiO2, CH2Cl2); further sepd. byTLC (SiO2, hexane-ethyl acetate);96%
With potassium tert-butylate In benzene byproducts: benzophenone; under N2; t-BuOK added to stirred soln. of Ph3SbCl2 and H2NC7H5O (molar ratio 2:1:1) in dry benzene; stirred at room temp. for 30 min; benzopinacol (1 equiv.) added; stirred at room temp. for 2 h; solvent evapd.; sepd. by column chromy. (SiO2, CH2Cl2); further sepd. byTLC (SiO2, hexane-ethyl acetate);92%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

H3COC6H4SCCl3

H3COC6H4SCCl3

C

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

D

triphenylantimony
603-36-1

triphenylantimony

E

chlorobenzene
108-90-7

chlorobenzene

Conditions
ConditionsYield
In tetrachloromethane byproducts: biphenyl; reflux; not isolated, GLC;A 36%
B 40%
C 22%
D 96%
E 33%
dibromogermane dioxane

dibromogermane dioxane

triphenylantimony dibromide
20265-30-9

triphenylantimony dibromide

A

germanium tetrabromide
13450-92-5

germanium tetrabromide

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene byproducts: dioxane; standing (room temperature, 24 h); liquid chromy.;A 93%
B 95%
vanadocene monochloride

vanadocene monochloride

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

bis(cyclopentadienyl)vanadium dichloride
12083-48-6

bis(cyclopentadienyl)vanadium dichloride

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene a soln. of Cp2VCl and Ph3SbCl2 (2:1) at 100°C for 3 h;A 95%
B 95%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

biphenyl
92-52-4

biphenyl

C

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

D

4-methoxyphenyl cyclohexyl sulfide
59693-94-6

4-methoxyphenyl cyclohexyl sulfide

E

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In cyclohexane reflux; not isolated, GLC;A 62%
B 3%
C 5%
D 31%
E 95%
antimony(III) chloride
10025-91-9

antimony(III) chloride

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
With phenylmagnesium bromide In tetrahydrofuran; benzene N2 atmosphere; addn. of SbCl3 to PhMgBr soln. (over 1.5-2 h, 85°C), heating (70-85°C, 1 h); ware addn., sepn. of org. layer, solvent removal, fractioning (vac., 200-205°C), crystn. (ethanol); elem. anal.;94%
With bromobenzene; sodium In toluene; benzene reflux for 5 to 6 h, SbCl3:C6H5BrNa in 0.5:1.5:4.35 rate; distn.;71.7%
With aniline; zinc In ethyl acetate treating diazotated aniline and SbCl3 with zinc powder;52%
Cr(CO)3{Sb(C6H5)3}3
79542-59-9

Cr(CO)3{Sb(C6H5)3}3

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In neat (no solvent) byproducts: Cr, Cr(CO)6, CO; in vacuo or under inert gas, heated at 230°C for 5 h; washed (benzene); TLC;94%
germanium(II) chloride dioxane

germanium(II) chloride dioxane

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

triphenylantimony
603-36-1

triphenylantimony

B

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

Conditions
ConditionsYield
In toluene byproducts: dioxane; standing (room temperature, 24 h); liquid chromy.;A 93%
B 91%
(C6H5)4SbSC6H4CH3*0.25CHCl3

(C6H5)4SbSC6H4CH3*0.25CHCl3

A

biphenyl
92-52-4

biphenyl

B

di(p-tolyl) disulfide
103-19-5

di(p-tolyl) disulfide

C

4-tolyl phenyl sulfide
3699-01-2

4-tolyl phenyl sulfide

D

triphenylantimony
603-36-1

triphenylantimony

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 4%
B 40%
C 50%
D 93%
E 15%
bis(phenylethynyl)ytterbium(II) tetrahydrofuranate
727679-11-0

bis(phenylethynyl)ytterbium(II) tetrahydrofuranate

iodotetraphenyl-λ5-stibane
16894-70-5

iodotetraphenyl-λ5-stibane

A

tetrakis(tetrahydrofurane)diiodidoytterbium(II)
106316-57-8, 166943-06-2

tetrakis(tetrahydrofurane)diiodidoytterbium(II)

B

phenylethynylytterbium(II) iodide tetrahydrofuranate
925457-74-5

phenylethynylytterbium(II) iodide tetrahydrofuranate

C

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In tetrahydrofuran Sb-compound in THF added to Yb-complex in THF, kept at room temp. for 24h under vac.; washed with hexane, dried in vac., solvent removed; elem. anal.;A 29%
B 71%
C 92.5%
bis(phenylethynyl)ytterbium(II) tetrahydrofuranate
727679-11-0

bis(phenylethynyl)ytterbium(II) tetrahydrofuranate

tetraphenylchloroantimony(V)
16894-68-1

tetraphenylchloroantimony(V)

A

YbCl2(C4H8O)4
925457-75-6

YbCl2(C4H8O)4

B

YbCl(C4H8O)4(C6H5C2)
925457-71-2

YbCl(C4H8O)4(C6H5C2)

C

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In tetrahydrofuran Sb-compound in THF added to Yb-complex in THF, kept at room temp. for 24h under vac.; washed with hexane, dried in vac., solvent removed; elem. anal.;A 25%
B 70%
C 91.5%
antimony(III) chloride
10025-91-9

antimony(III) chloride

triphenylantimony
603-36-1

triphenylantimony

diphenylantimony(III) chloride
2629-47-2

diphenylantimony(III) chloride

Conditions
ConditionsYield
In neat (no solvent) for 72h;100%
In neat (no solvent) for 3h;100%
Stage #1: antimony(III) chloride; triphenylantimony at 20℃; for 72h; Inert atmosphere;
Stage #2: for 336h; Cooling;
95%
antimony(III) chloride
10025-91-9

antimony(III) chloride

triphenylantimony
603-36-1

triphenylantimony

dichlorophenylstibine
5035-52-9

dichlorophenylstibine

Conditions
ConditionsYield
In neat (no solvent) for 72h;100%
In neat (no solvent) for 3h;100%
In neat (no solvent) for 3h; Schlenk technique; Inert atmosphere;100%
triphenylantimony
603-36-1

triphenylantimony

thiophenol
108-98-5

thiophenol

(C6H5)2SbSC6H5
28609-59-8

(C6H5)2SbSC6H5

Conditions
ConditionsYield
In benzene threefold excess of C6H5SH used, heating at 50°C for 15 h; with and without addn. of t-butyl hyponitrite: radical mechanism postulated;100%
In benzene threefold excess of C6H5SH used, heating at 50°C for 15 h; with and without addn. of t-butyl hyponitrite: radical mechanism postulated;100%
In benzene Kinetics; mole ratio 3:1, 15 h;>99
In benzene Kinetics; mole ratio 3:1, 15 h;>99
triphenylantimony
603-36-1

triphenylantimony

thallium (III) chloride
13453-32-2

thallium (III) chloride

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

Conditions
ConditionsYield
In ethanol; toluene100%
In ethanol; toluene100%
chloro(1,5-cyclooctadiene)rhodium(I) dimer

chloro(1,5-cyclooctadiene)rhodium(I) dimer

dichloromethane
75-09-2

dichloromethane

triphenylantimony
603-36-1

triphenylantimony

Rh(C8H12)(Sb(C6H5)3)2Cl*0.5CH2Cl2

Rh(C8H12)(Sb(C6H5)3)2Cl*0.5CH2Cl2

Conditions
ConditionsYield
In ethanol (under Ar, Schlenk); Rh-complex added to refluxing soln. of Sb(C6H5)3 inEtOH; ppt. filtered, washed with CH2Cl2/hexane, dried in vacuo; elem. anal.;100%
di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

triphenylantimony
603-36-1

triphenylantimony

Rh(Sb(C6H5)3)2(CO)Cl
17967-63-4

Rh(Sb(C6H5)3)2(CO)Cl

Conditions
ConditionsYield
In dichloromethane (under Ar or N2, Schlenk); Rh-complex and Sb(C6H5)3 dissolved in CH2Cl2,stirred for 2 h; reduced to dryness, residue stirred in hexane, ppt. filtered, dried in vacuo; elem. anal.;100%
methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

triphenylantimony
603-36-1

triphenylantimony

A

methyltriphenylstibonium tetrafluoroborate
3802-09-3

methyltriphenylstibonium tetrafluoroborate

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 react. (Ph3BiMe)(BF4) and SbPh3 in CDCl3 at room temp.; detn. by 1H NMR;A 100%
B 100%
trans-diiodo(N-pyridine)[1-methyl-3-benzylimidazol-2-ylidene]platinum(II)

trans-diiodo(N-pyridine)[1-methyl-3-benzylimidazol-2-ylidene]platinum(II)

triphenylantimony
603-36-1

triphenylantimony

C47H42IN2PtSb2(1+)*I(1-)

C47H42IN2PtSb2(1+)*I(1-)

Conditions
ConditionsYield
In ethanol at 55℃; Inert atmosphere; Schlenk technique;100%
triphenylantimony
603-36-1

triphenylantimony

tri-tert-butyl gallium
55681-99-7

tri-tert-butyl gallium

C30H42GaSb

C30H42GaSb

Conditions
ConditionsYield
In chloroform at -30℃; for 120h; Inert atmosphere; Glovebox; Schlenk technique;100%
potassium (3-(benzyloxy)phenyl)trifluoroborate

potassium (3-(benzyloxy)phenyl)trifluoroborate

triphenylantimony
603-36-1

triphenylantimony

3-(benzyloxy)-1,1’-biphenyl
123689-52-1

3-(benzyloxy)-1,1’-biphenyl

Conditions
ConditionsYield
With ferrocenium hexafluorophosphate; bis(tri-t-butylphosphine)palladium(0); cesium fluoride In tetrahydrofuran at 60℃; Inert atmosphere; Schlenk technique; Glovebox;100%
triphenylantimony
603-36-1

triphenylantimony

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With cyclododecane; palladium diacetate In chloroform at 70℃; for 14h; other solvents, other temp., other times;99%
With triethylamine; palladium diacetate In tetrahydrofuran at 65℃; for 1.5h;97%
With 2-thioxo-3H-1,3-benzothiazole; copper diacetate; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere;11 %Chromat.
triphenylantimony
603-36-1

triphenylantimony

acetic acid
64-19-7

acetic acid

triphenylantimony(V) diacetate
1538-62-1, 34716-94-4

triphenylantimony(V) diacetate

Conditions
ConditionsYield
With dihydrogen peroxide In acetic acid H2O2 added to soln. of (C6H5)3Sb in CH3CO2H; washed with hexane, dried;99%
With tert.-butylhydroperoxide In diethyl ether byproducts: t-BuOH, H2O; t-BuOOH was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O, kept in the dark for 24 h at room temp.; solvent was distilled off under reduced pressure, recrystd. from CHCl3/hexane;90%
With dihydrogen peroxide In diethyl ether; isopropyl alcohol H2O2 was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O and i-PrOH, kept in the dark for 3 h at room temp.; filtered, washed with i-PrOH, recrystd. from CHCl3/hexane;85%
copper diacetate In pyridine; toluene byproducts: C6H6; mixt. of starting materials and catalyst in soln. sealed in an ampul without evacuation, heated (8h, 110. degree.C); liquid portion distd. at reduced pressure;
triphenylantimony
603-36-1

triphenylantimony

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

diphenylantimony(III) chloride
2629-47-2

diphenylantimony(III) chloride

Conditions
ConditionsYield
In chloroform reflux under CO2;99%
In chloroform reflux under CO2;99%
2-furanoic acid
88-14-2

2-furanoic acid

triphenylantimony
603-36-1

triphenylantimony

triphenylantimony bis(2-furoinate)
126117-45-1

triphenylantimony bis(2-furoinate)

Conditions
ConditionsYield
With H2O2 In diethyl ether; water 42% aq. soln. of hydrogen peroxide added to reagent mixt. at 20°C, stored for 12 h; solvent evapd., recrystd. (toluene), elem. anal.;99%
triphenylantimony
603-36-1

triphenylantimony

3,4,5-trifluorobenzoic acid
121602-93-5

3,4,5-trifluorobenzoic acid

(C6H5)3Sb(OCOC6H2F3)2
460752-06-1

(C6H5)3Sb(OCOC6H2F3)2

Conditions
ConditionsYield
With dihydrogen peroxide In diethyl ether; water byproducts: H2O; react. of antimony compd. and acid with aq. H2O2 at room temp. in ether; elem. anal.;99%
triphenylantimony
603-36-1

triphenylantimony

3,4,5-trifluorobenzoic acid
121602-93-5

3,4,5-trifluorobenzoic acid

triphenylantimony bis(3,4,5-trifluorobenzoate)

triphenylantimony bis(3,4,5-trifluorobenzoate)

Conditions
ConditionsYield
With H2O2 In diethyl ether (C6F3H2)COOH and 30% aq. H2O2 added to soln. of Ph3Sb in ether; kept at 20°C for 12 h; crystals filtered off; dried; elem. anal.;99%
hydrogenchloride
7647-01-0

hydrogenchloride

[Mo3(PdCl)S4(H2O)9](3+)

[Mo3(PdCl)S4(H2O)9](3+)

water
7732-18-5

water

triphenylantimony
603-36-1

triphenylantimony

[Mo3(PdSb(C6H5)3)S4(H2O)5Cl4]

[Mo3(PdSb(C6H5)3)S4(H2O)5Cl4]

Conditions
ConditionsYield
In hydrogenchloride; methanol a soln. of Sb compd. (methanol) added to a soln. of cluster (aq. HCl), kept in open vial for 2 d; crysts. filtered, dried (vac., P2O5); elem. anal.;99%
N-chlorotriphenylphosphoraneimine
80166-23-0

N-chlorotriphenylphosphoraneimine

triphenylantimony
603-36-1

triphenylantimony

triphenylphosphinimino-triphenylstibonium chloride

triphenylphosphinimino-triphenylstibonium chloride

Conditions
ConditionsYield
In dichloromethane with exclusion of moisture, 1 equiv. of P-compd. in CH2Cl2 was added dropwise to CH2Cl2 soln. of Sb-compd.; soln. was concd. in dry N2-stream, several days at room temp., crystals were filtered off, filtrate was evapd. to dryness;99%
tris(2-methoxyphenyl)bismuthane oxide

tris(2-methoxyphenyl)bismuthane oxide

triphenylantimony
603-36-1

triphenylantimony

A

tris(2-methoxyphenyl)bismuthine
83724-41-8

tris(2-methoxyphenyl)bismuthine

B

triphenyl antimony oxide
4756-75-6

triphenyl antimony oxide

Conditions
ConditionsYield
In dichloromethane Ph3Sb (2 equiv.) added to CH2Cl2 soln. of Bi compd. at room temp.; reacted for 30 min; concd. under reduced pressure; detd. by (1)H NMR spectra;A 99%
B 99%
hydrogenchloride
7647-01-0

hydrogenchloride

[Mo3(NiCl)S4(H2O)9](3+)

[Mo3(NiCl)S4(H2O)9](3+)

triphenylantimony
603-36-1

triphenylantimony

[Mo3(NiSb(C6H5)3)S4(H2O)5Cl4]

[Mo3(NiSb(C6H5)3)S4(H2O)5Cl4]

Conditions
ConditionsYield
In hydrogenchloride; methanol a soln. of Sb compd. (methanol) added to a soln. of cluster (aq. HCl), kept in open vial for 2 d; crysts. filtered, dried (vac., P2O5); elem. anal.;99%
triphenylantimony
603-36-1

triphenylantimony

phenylpropyolic acid
637-44-5

phenylpropyolic acid

triphenylantimony bis(phenylpropiolate)

triphenylantimony bis(phenylpropiolate)

Conditions
ConditionsYield
With tert.-butylhydroperoxide In diethyl ether for 12h;99%
With tert.-butylhydroperoxide In diethyl ether for 12h; Heating;99%
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

triphenylantimony
603-36-1

triphenylantimony

dichloro(η5-pentamethylcyclopentadienyl)(triphenylstibine)rhodium(III)
848236-31-7

dichloro(η5-pentamethylcyclopentadienyl)(triphenylstibine)rhodium(III)

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;99%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

triphenylantimony
603-36-1

triphenylantimony

C28H30Cl2IrSb

C28H30Cl2IrSb

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;99%
triphenylantimony
603-36-1

triphenylantimony

phenylpropyolic acid
637-44-5

phenylpropyolic acid

triphenylantimony bis(phenylpropiolate)

triphenylantimony bis(phenylpropiolate)

Conditions
ConditionsYield
With tert.-butylhydroperoxide In water for 12h;99%

603-36-1Relevant articles and documents

Razuvaev, G. A.,Osanova, N. A.

, p. 77 - 82 (1972)

Thermochemistry of Sulfur Atom Transfer. Enthalpies of Reaction of Phosphines with Sulfur, Selenium, and Tellurium, and of Desulfurization of Triphenylarsenic Sulfide, Triphenylantimony Sulfide, and Benzyl Trisulfide

Capps, Kenneth B.,Wixmerten, Bodo,Bauer, Andreas,Hoff, Carl D.

, p. 2861 - 2864 (1998)

The enthalpies of reaction of neat PBu3 with solid sulfur (-27.1 ± 0.5 kcal/mol), selenium (-20.0 ± 0.6 kcal/ mol), and tellurium (-4.9 ± 0.6 kcal/mol) have been measured by solution calorimetry. The enthalpies of reaction of a series of phosphines with sulfur in toluene solution have been measured as follows (values in kcal/mol): PCy3 = -30.9 ± 1.9, PBu3 = -28.9 ± 0.3, PMe3 = -27.1 ± 0.4, PMe2Ph = -26.0 ± 0.5, PMePh2 = -23.8 ± 0.3. PPh3 = -21.5 ± 0.3. These values correlate with literature data for enthalpies of protonation and indicate that P to S σ donation is probably the dominant factor in determining the R3P=S bond strength, estimates for which range from 88 to 98 kcal/mol. The enthalpies of S atom transfer to PPh3 by S=AsPPh3 and S=SbPh3 in toluene solution are -17.7 ± 1.2 and -21.5 ± 1.0 kcal/mol, respectively. The enthalpy of removal of the central S atom from BzSSSBz by PCy3, yielding BzSSBz and S=PCy3, is -29.0 ± 1.8 kcal/mol. These data are used to establish a range of enthalpies of S atom transfer in these compounds which spans 31 kcal/mol from S=SbPPh3 to S=PCy3.

Synthesis method of triphenyl antimony

-

Paragraph 0061-0068; 0104-0109, (2018/11/03)

The invention discloses a synthesis method of triphenyl antimony, which comprises the following steps: adding higher fatty acid or higher fatty acid salt and adding sodium to organic solvent under theprotection of an inert gas, performing refluxing reaction and cooling to room temperature; slowly adding halogenated benzene into the obtained solution, then slowly dripping halogenated benzene solution of antimonous chloride, reaction under stirring, filtering the obtained reaction solution, evaporating organic solvent and halogenated benzene in the obtained filtrate under normal pressure to obtain a crude triphenyl antimony product; dissolving the crude product with petroleum ether, filtrating, concentrating the obtained filtrate and then freezing for crystallization to obtain triphenyl antimony. Triphenyl antimony is synthesized by the method disclosed by the invention, the utilization rate of raw materials is high, the use of high-pollution catalysts is avoided, the discharge of threewastes is reduced, production cost is reduced, the industrial application value is high, and the product has high purity and high yield.

Establishing the coordination chemistry of antimony(v) Cations: Systematic assessment of Ph4Sb(OTf) and Ph3Sb(OTf)2 as Lewis acceptors

Robertson, Alasdair P. M.,Chitnis, Saurabh S.,Jenkins, Hilary A.,McDonald, Robert,Ferguson, Michael J.,Burford, Neil

, p. 7902 - 7913 (2015/05/20)

The coordination chemistry of the stiboranes Ph4Sb(OTf) (1 a, OTf = OSO2CF3) and Ph3Sb(OTf)2 (3) with Lewis bases has been investigated. The significant steric encumbrance of the Sb center in 1 a precludes interaction with most ligands, but the relatively low steric demands of 4-methylpyridine-N-oxide (OPyrMe) and OPMe3 enabled the characterization of [Ph4Sb(OPyrMe)][OTf] (2 a) and [Ph4Sb(OPMe3)][OTf] (2 b), rare examples of structurally characterized complexes of stibonium acceptors. In contrast, 3 was found to engage a variety of Lewis bases, forming stable isolable complexes of the form [Ph3Sb(donor)2][OTf]2 [donor=OPMe3 (6 a), OPCy3 (6 b, Cy=cyclohexyl), OPPh3 (6 c), OPyrMe (6 d)], [Ph3Sb(dmap)2(OTf)][OTf] (6 e, dmap=4-(dimethylamino)pyridine) and [Ph3Sb(donor)(OTf)][OTf] [donor=1,10-phenanthroline (7 a) or 2,2′-bipy (7 b, bipy=bipyridine)]. These compounds exhibit significant structural diversity in the solid-state, and undergo ligand exchange reactions in line with their assignment as coordination complexes. Compound 3 did not form stable complexes with phosphine donors, with reactions instead leading to redox processes yielding SbPh3 and products of phosphine oxidation.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 603-36-1