6031-78-3Relevant academic research and scientific papers
Ionic liquids of superior thermal stability
Cassity, Cody G.,Mirjafari, Arsalan,Mobarrez, Niloufar,Strickland, Katie J.,O'Brien, Richard A.,Davis, James H.
, p. 7590 - 7592 (2013/08/28)
In a head-to-head study, ILs based upon tetraarylphosphonium cations exhibit superior long-term thermal stability compared to familiar salts based upon imidazolium, quaternary ammonium, or tetraalkylphosphonium cations. The Royal Society of Chemistry.
Palladium-catalyzed synthesis of functionalized tetraarylphosphonium salts
Marcoux, David,Charette, Andre B.
, p. 590 - 593 (2008/09/17)
(Chemical Equation Presented) An efficient method to synthesize functionalized tetraarylphosphonium salts is described. This palladium-catalyzed coupling reaction between aryl iodides, bromides, or triflates and triphenylphosphine generates phosphonium salts in high yields. The coupling is compatible with a variety of functional groups such as alcohols, ketones, aldehydes, phenols, and amides.
Convenient Preparation of Tetraarylphosphonium Halides
Migita, Toshihiko,Nagai, Tohru,Kiuchi, Kazuhiko,Kosugi, Masanori
, p. 2869 - 2870 (2007/10/02)
Tetraarylphosphonium halides, particularly iodides, can be conveniently prepared by the Pd-catalyzed reaction of aryl halides and triarylphosphines in good yields.
