603129-11-9Relevant academic research and scientific papers
Enantiospecific first total synthesis of (+)-cis,anti,cis-3-hydroxy-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.0 2,6]-dodecan-9-yl senecioate, the optical antipode of a natural thapsane isolated from Thapsia villosa
Srikrishna,Anebouselvy
, p. 1031 - 1034 (2003)
The enantiospecific first total synthesis of 10-hydroxy-10,11-epoxythapsan-5-yl senecioate (+)-1f, the enantiomer of the natural thapsane isolated from Thapsia villosa var minor, has been accomplished starting from (R)-carvone.
Enantiospecific total synthesis of ent-5-senecioyloxy-10,11-epoxythapsan- 10-ol
Srikrishna,Anebouselvy
experimental part, p. 776 - 788 (2011/01/04)
Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,11-epoxythapsan-10-ol has been described. (R)-Carvone has been employed as the chiral starting material and a combination of intramolecular alkyation and Criegee fr
