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Tri-t-butylcyclopropenyltetrafluoroborate is a complex organic compound with the chemical formula C13H21BF4. It is a derivative of cyclopropene, a three-membered cyclic hydrocarbon, with three t-butyl groups attached to the carbon atoms of the cyclopropane ring. The tetrafluoroborate ion (BF4-) is a stable, non-coordinating anion that forms a salt with the tri-t-butylcyclopropenyl cation. Tri-t-butylcyclopropenyltetrafluoroborate is of interest in organic chemistry due to its unique structure and potential applications in the synthesis of various organic compounds. It is typically synthesized through the reaction of cyclopropene with t-butyllithium and subsequent treatment with boron trifluoride etherate. Tri-t-butylcyclopropenyltetrafluoroborate is a colorless, crystalline solid that is sensitive to moisture and air, and should be handled under an inert atmosphere.

60391-90-4

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60391-90-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 60391-90-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,0,3,9 and 1 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 60391-90:
(7*6)+(6*0)+(5*3)+(4*9)+(3*1)+(2*9)+(1*0)=114
114 % 10 = 4
So 60391-90-4 is a valid CAS Registry Number.

60391-90-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,2,3-tri-tert-butylcyclopropenylium tetrafluoroborate

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

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More Details:60391-90-4 SDS

60391-90-4Downstream Products

60391-90-4Relevant academic research and scientific papers

Small Rings, 74. - Hexa-tert-butyl-3,3'-bicyclopropenyl

Maier, Guenter,Schick, Andreas,Bauer, Ines,Boese, Roland,Nussbaumer, Michael

, p. 2111 - 2118 (2007/10/02)

Title compound 3 can be prepared by reductive coupling of tri-tert-butylcyclopropenylium tetrafluoroborate (4a) with lithium.Upon treatment with AgBF4 3 does not undergo valence isomerization to the Dewar form of hexa-tert-butylbenzene (2) but is reoxidized under backformation of substrate 4a.The photochemical behavior of 6 is also unusual: Irradiation at room temperature results in gas evolution.However, instead of 7, the ?-diketone 5 is isolated.Monoketone 7 is only formed if 6 is irradiated in an organic matrix at -196 deg C. Key words: Steric hindrance / Redox chemistry / Bicyclopropenyl / Small rings

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