60433-86-5Relevant academic research and scientific papers
Synthesis and Interconversion of, and Restricted Rotation in, Phenyl Complexes of Ruthenium(II)
Probitts, E. Jane,Saunders, David R.,Stone, Michael H.,Mawby, Roger J.
, p. 1167 - 1174 (2007/10/02)
The preparation and characterization of a range of phenyl complexes of ruthenium(II) are reported.For many of the complexes there is a substantial barrier to rotation of the phenyl ligand about the metal-phenyl bond, and n.m.r. studies have shown how the rate of rotation is affected by changes in the ligands in the complexes.Reaction of complexes with phosphorus or arsenic ligands L provides a convenient route to : 31P and 13C n.m.r. studies have demonstrated the sequence of steps involved and the stereochemistry of the intermediates, showing the influence of the trans-labilizing and trans-directing effects of the phenyl ligand.
