60444-80-6Relevant articles and documents
Biotransformation of caryophyllene oxide by Botrytis cinerea
Duran, Rosa,Corrales, Elena,Hernandez-Galan, Rosario,Collado, Isidro G.
, p. 41 - 44 (2007/10/03)
Biotransformation of caryophyllene oxide (1) with B. cinerea afforded 15 products (2-16). Ten of these (3-5, 7, 9-11, and 14-16) are reported here for the first time. The main reaction paths involved stereoselective epoxidation at C-8/C-13 and hydroxylation at C-7. A rearranged compound was found, which was a cyclization product 16 possessing the caryolane skeleton.