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6047-99-0 Usage

Synthesis Reference(s)

Tetrahedron Letters, 26, p. 1599, 1985 DOI: 10.1016/S0040-4039(00)98562-9

Check Digit Verification of cas no

The CAS Registry Mumber 6047-99-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,0,4 and 7 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 6047-99:
(6*6)+(5*0)+(4*4)+(3*7)+(2*9)+(1*9)=100
100 % 10 = 0
So 6047-99-0 is a valid CAS Registry Number.

6047-99-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-phenyloctan-3-one

1.2 Other means of identification

Product number -
Other names Pentylphenethyl ketone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6047-99-0 SDS

6047-99-0Relevant articles and documents

Formation of pyrrolidines by the titanocene(II)-promoted intramolecular reaction of N-[3,3-bis(phenylthio)propyl]anilides

Takeda, Takeshi,Saito, Jun,Tsubouchi, Akira

, p. 5571 - 5574 (2003)

The reaction of anilides with the titanium carbene complexes generated by the desulfurization of thioacetals with the titanocene(II) species Cp2Ti[P(OEt)3]2 produced the corresponding enamines. Unusual formation of pyrroli

Palladium Catalysis for Aerobic Oxidation Systems Using Robust Metal–Organic Framework

Li, Jiawei,Liao, Jianhua,Ren, Yanwei,Liu, Chi,Yue, Chenglong,Lu, Jiaming,Jiang, Huanfeng

supporting information, p. 17148 - 17152 (2019/11/03)

Described here is a new and viable approach to achieve Pd catalysis for aerobic oxidation systems (AOSs) by circumventing problems associated with both the oxidation and the catalysis through an all-in-one strategy, employing a robust metal–organic framework (MOF). The rational assembly of a PdII catalyst, phenanthroline ligand, and CuII species (electron-transfer mediator) into a MOF facilitates the fast regeneration of the PdII active species, through an enhanced electron transfer from in situ generated Pd0 to CuII, and then CuI to O2, trapped in the framework, thus leading to a 10 times higher turnover number than that of the homogeneous counterpart for Pd-catalyzed desulfitative oxidative coupling reactions. Moreover, the MOF catalyst can be reused five times without losing activity. This work provides the first exploration of using a MOF as a promising platform for the development of Pd catalysis for AOSs with high efficiency, low catalyst loading, and reusability.

NNN pincer Ru(II)-complex-catalyzed α-alkylation of ketones with alcohols

Cao, Xiao-Niu,Wan, Xiao-Min,Yang, Fa-Liu,Li, Ke,Hao, Xin-Qi,Shao, Tian,Zhu, Xinju,Song, Mao-Ping

, p. 3657 - 3668 (2018/04/14)

A series of novel ruthenium(II) complexes supported by a symmetrical NNN ligand were prepared and fully characterized. These complexes exhibited good performance in transfer hydrogenation to form new C-C bonds using alcohols as the alkylating agents, generating water as the only byproduct. A broad range of substrates, including (hetero)aryl- or alkyl-ketones and alcohols, were well tolerated under the optimized conditions. Notably, α-substituted methylene ketones were also investigated, which afforded α-branched steric hindrance products. A potential application of α-alkylation of methylene acetone to synthesize donepezil was demonstrated, which provided the desired product in 83% yield. Finally, this catalytic system could be applied to a one-pot double alkylation procedure with sequential addition of two different alcohols. The current protocol is featured with several characteristics, including a broad substrate scope, low catalyst (0.50 mol %) loadings, and environmental benignity.

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