604757-20-2

Upstream product

• 963-15-5 (Z)-1,2-bis(phenylsulfonyl)ethene 
• 604757-18-8 methyl 2,3-di-O-benzyl-6-thio-α-D-glucopyranoside 
• 894428-35-4 methyl 2,3-di-O-benzyl-6-S-[(Z)-2-(phenylsulfonyl)-vinyl]-6-thio-α-D-glucopyranoside 
• 894428-34-3 methyl 2,3-di-O-benzyl-6-S-[(E)-2-(phenylsulfonyl)-vinyl]-6-thio-α-D-glucopyranoside 
• 894428-26-3 methyl 2,3-di-O-benzyl-6-S-(N,N-dimethyldithiocarbamoyl)-6-thio-α-D-glucopyranoside 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 894428-35-4 methyl 2,3-di-O-benzyl-6-S-[(Z)-2-(phenylsulfonyl)-vinyl]-6-thio-α-D-glucopyranoside 
• 604757-18-8 methyl 2,3-di-O-benzyl-6-thio-α-D-glucopyranoside 
• 894428-34-3 methyl 2,3-di-O-benzyl-6-S-[(E)-2-(phenylsulfonyl)-vinyl]-6-thio-α-D-glucopyranoside 

Relevant academic research and scientific papers

Investigating thio-analogues of PSE acetals: A more complex reaction

The reaction of hydroxylated thiols with 1,2-bis-phenylsulfonylethylene was investigated: in contrast with diols, a more complex reaction was observed and application to carbohydrate-derived PSE oxathianes was envisaged.

Vinyl bis-sulfone methodology in thiosugars: selective access to chiral thiovinyl sulfones and PSE oxathianes

Based on the vinyl bis-sulfone methodology previously developed to synthesize PSE acetals, an original approach to homochiral carbohydrate-derived PSE 1,3-oxathianes is described. The ready formation of intermediate phenylsulfonylvinyl sulfides, which hav