60538-01-4Relevant academic research and scientific papers
Nucleophilic vinylic substitutions of (Z)-(2-aroyloxyvinyl)phenyl- λ3-iodanes with tetrabutylammonium halides: Vinylic S N2 reactions and ligand coupling on iodine(III)
Ochiai, Masahito,Nishi, Yoshio,Hirobe, Masaya
, p. 1863 - 1866 (2005)
Treatment of (Z)-(β-benzoyloxyvinyl)phenyl-λ3- iodanes, readily prepared from ethynyl(phenyl)(tetrafluoroborato)- λ3-iodane via stereoselective Michael-type addition of benzoic acids in methanol in the presence of sodium benzoates, with tetrabutylammonium halides in THF at 65°C results in a vinylic SN2 reaction to give the inverted (E)-β-benzoyloxyvinyl halides in high yields.
