60541-32-4Relevant academic research and scientific papers
Corresponding amine nitrile and method of manufacturing thereof
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Paragraph 0125; 0126; 0129; 0130, (2018/05/24)
The present invention relates to a nitrile manufacturing method, which has characteristics of significantly-reduced ammonia source consumption, low environmental pressure, low energy consumption, low production cost, high nitrile purity, high nitrile yield and the like compared with the method in the prior art, wherein nitrile having a complicated structure can be obtained through the method. The present invention further relates to a method for producing a corresponding amine from the nitrile.
Corresponding amine nitrile and method of manufacturing thereof
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Paragraph 0122; 0123; 0127, (2018/05/24)
The invention relates to a preparation method of nitrile. Compared with the prior art, the preparation method has the characteristics of obvious reduction of the usage amount of ammonia sources, low environmental pressure, low energy consumption, low production cost, high purity and yields of nitrile products, and the like, and can be used for obtaining nitrile with a more complex structure. The invention also relates to a method for preparing corresponding amine with nitrile.
Corresponding amine nitrile and method of manufacturing thereof (by machine translation)
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Paragraph 0123-0124; 0127-0128, (2017/10/22)
The invention relates to a method of manufacturing one kind of nitrile, compared with the prior art, has significantly reduced the amount of ammonia, the environmental pressure of the small, low energy consumption, low production cost, nitrile product purity and yield and the like, and can obtain more complex structure of the nitriles. The invention also relates to the corresponding amine by the nitrile manufacture method. (by machine translation)
Structural evolution of 2D microporous covalent triazine-based framework toward the study of high-performance supercapacitors
Hao, Long,Ning, Jing,Luo, Bin,Wang, Bin,Zhang, Yunbo,Tang, Zhihong,Yang, Junhe,Thomas, Arne,Zhi, Linjie
supporting information, p. 219 - 225 (2015/01/30)
A series of nitrogen-containing micropore-donimated materials, porous triazine-based frameworks (PTFs), are constructed through the structural evolution of a 2D microporous covalent triazine-based framework. The PTFs feature predictable and controllable nitrogen doping and pore structures, which serve as a model-like system to more deeply understand the heteroatom effect and micropore effect in ionic liquid-based supercapacitors. The experimental results reveal that the nitrogen doping can enhance the supercapacitor performance mainly through affecting the relative permittivity of the electrode materials. Although microspores' contribution is not as obvious as the doped nitrogen, the great performances of the micropore-dominated PTF suggest that micropore-dominated materials still have great potential in ionic liquid-based supercapacitors.
Single-walled polytetrazolate metal-organic channels with high density of open nitrogen-donor sites and gas uptake
Lin, Qipu,Wu, Tao,Zheng, Shou-Tian,Bu, Xianhui,Feng, Pingyun
, p. 784 - 787 (2012/03/07)
The self-assembly between zinc dimer and 1,3,5-tris(2H-tetrazol-5-yl) benzene (H3BTT), promoted by a urea derivative, leads to a highly porous 3D framework with a large percentage (67%) of N-donor sites unused for bonding with metals. The material exhibits high gas storage capacity (ca. 1.89 wt % H2 at 77 K and 1 atm; 98 cm3/g CO2 at 273 K and 1 atm), even in the absence of open metal sites. The high percentage of open N-donor sites, coupled with the low framework density resulting from single-walled channels, is believed to contribute to the high uptake capacity.
Tris(triorganostannyltetrazoles): Synthesis and supramolecular structures
Hill, Michael,Mahon, Mary F.,Molloy, Kieran C.
, p. 1857 - 1865 (2007/10/03)
Six trifunctional triorganotin tetrazoles, (R3SnN4CCH2CH2)3C(NO 2) and 1,3,5-(R3SnN4C)3C6H3(R = Me, Et or Bu), have been synthesised by a cycloaddition route from SnR3(N3) and either (NCCH2CH2)3C(NO2) or 1,3,5-(NC)3C6H3 as dipblarophile. The compounds have been characterised by 1H, 13C, 119Sn NMR and 119Moessbauer spectroscopies, while the crystal structures of the tributyltin examples of each series reveal they adopt layered supramolecular arrays.
