60550-55-2

Upstream product

• 70-11-1 α-bromoacetophenone 
• 636-04-4 N-Phenylbenzothioamide 

Downstream Products

• 88559-26-6 5-benzoyl-4-methylthio-1,3-dithiole-2-thione 
• 63255-41-4 (Z)-1,3-diphenyl-3-(phenylamino)prop-2-en-1-one 
• 1338379-32-0 2,3,4-triphenylthiazolium bromide 
• 1338379-36-4 2,3,4-triphenylthiazolium trifluoromethanesulfonate 

Relevant academic research and scientific papers

Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes

The first examples of thiazol-5-ylidene complexes featuring group 9, 10 and 11 metal centers, have been prepared by deprotonation of a series of 2,3,4-triaryl-susbtituted thiazolium salts in the presence of the corresponding transition metal precursor.

One-pot eschenmoser episulfide contractions in DMSO: Applications to the synthesis of fuligocandins A and B and a number of vinylogous amides

Practical total syntheses of the natural products fuligocandin A (2a) and fuligocandin B (3) have been achieved through a convergent strategy depending on the Eschenmoser episulfide contraction as a key step. Conducting the reaction in DMSO proved to be an efficient and general method for the synthesis of a variety of vinylogous amides, such as azepan-2- ylidenepropan-2-one. 2011 American Chemical Society.