605668-77-7

Upstream product

• 110426-22-7 5-benzyloxy-1-(S_R)-(4-methylphenylsulfinyl)-(2R,3E)-penten-2-ol 
• 110426-21-6 (E)-5-Benzyloxy-1-((R)-toluene-4-sulfinyl)-pent-3-en-2-one 

Downstream Products

• 605668-78-8 4-[2-benzyloxy-1-bromo-(1S)-ethyl]-2,2-dimethyl-5-(S_S)-(4-methylphenylsulfinylmethyl)-(4R,5R)-1,3-dioxolane 
• 900792-42-9 (S)-2-Benzyloxy-1-[(4S,5R)-2,2-dimethyl-5-((S)-toluene-4-sulfinylmethyl)-[1,3]dioxolan-4-yl]-ethanol 
• 900792-40-7 Benzoic acid (1S,2R,3R)-1-benzyloxymethyl-2,3-dihydroxy-4-((S)-toluene-4-sulfinyl)-butyl ester 
• 900792-41-8 Benzoic acid (S)-2-benzyloxy-1-[(4S,5R)-2,2-dimethyl-5-((S)-toluene-4-sulfinylmethyl)-[1,3]dioxolan-4-yl]-ethyl ester 
• 900792-43-0 {(S)-2-Benzyloxy-1-[(4R,5R)-2,2-dimethyl-5-((S)-toluene-4-sulfinylmethyl)-[1,3]dioxolan-4-yl]-ethoxy}-tert-butyl-dimethyl-silane 
• 610316-29-5 tert-butoxycarbonylamino-[5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetic acid 
• 610316-27-3 [(4S,5S)-5-((R)-1-Azido-2-benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy]-tert-butyl-diphenyl-silane 
• 610316-28-4 {1-[5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2-hydroxy-ethyl}-carbamic acid tert-butyl ester 
• 610316-26-2 [(4S,5S)-5-((R)-1-Azido-2-benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-methanol 
• 605668-79-9 4-[1-azido-2-benzyloxy-(1R)-ethyl]-2,2-dimethyl-5-(S_S)-(4-methylphenylsulfinylmethyl)-(4R,5R)-1,3-dioxolane 
• 205449-13-4 Methyl 5-O-tert-butyldiphenylsilyl-2-(tert-butoxycarbonyl)amino-2-deoxy-3,4-O-isopropylidene-L-xylonate 
• 900792-39-4 (R)-1-((2R,3R)-3-Benzyloxymethyl-oxiranyl)-2-((S)-toluene-4-sulfinyl)-ethanol 

Relevant academic research and scientific papers

Novel, efficient and stereospecific synthesis of xylo-(2R,3S,4S)-phytosphingosine and threo-(2R,3R)-sphingosine

The stereo- and regioselective elaboration of a bromohydrin from an olefinic precursor and Pummerer ene reaction for carbon-carbon bond formation are the key steps in a novel and flexible synthesis of xylo-phytosphingosine and threo-sphingosine.

The sulfinyl moiety as an internal nucleophile. Part 8: Efficient, stereospecific synthesis of (+)-polyoxamic acid

A straightforward and stereospecific synthesis of (+)-polyoxamic acid is disclosed. The key step of the synthesis involves the regio- and stereospecific bromohydration of an olefin via intramolecular participation by the sulfinyl group.