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60573-58-2

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60573-58-2 Usage

Synthesis Reference(s)

Tetrahedron Letters, 37, p. 1941, 1996 DOI: 10.1016/0040-4039(96)00309-7

Check Digit Verification of cas no

The CAS Registry Mumber 60573-58-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,0,5,7 and 3 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 60573-58:
(7*6)+(6*0)+(5*5)+(4*7)+(3*3)+(2*5)+(1*8)=122
122 % 10 = 2
So 60573-58-2 is a valid CAS Registry Number.

60573-58-2Relevant articles and documents

Ruthenium-Catalyzed Dehydrogenation Through an Intermolecular Hydrogen Atom Transfer Mechanism

Huang, Lin,Bismuto, Alessandro,Rath, Simon A.,Trapp, Nils,Morandi, Bill

supporting information, p. 7290 - 7296 (2021/03/01)

The direct dehydrogenation of alkanes is among the most efficient ways to access valuable alkene products. Although several catalysts have been designed to promote this transformation, they have unfortunately found limited applications in fine chemical synthesis. Here, we report a conceptually novel strategy for the catalytic, intermolecular dehydrogenation of alkanes using a ruthenium catalyst. The combination of a redox-active ligand and a sterically hindered aryl radical intermediate has unleashed this novel strategy. Importantly, mechanistic investigations have been performed to provide a conceptual framework for the further development of this new catalytic dehydrogenation system.

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