60586-51-8

Upstream product

• 92876-98-7 methyl pentane-1-sulfinate 
• 5720-05-8 4-methylphenylboronic acid 
• 497069-72-4 tert-butyl-dimethyl-[1-methyl-4-(toluene-4-sulfinyl)-butoxy]-silane 
• 62957-47-5 1-bromo-4-(tert-butyldimethylsilyloxy)pentane 
• 1517-82-4 (1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate 
• 497069-56-4 O-[1-methyl-4-(p-toluenesulfinyl)butyl] 1H-imidazole-1-carbothioate 

Relevant academic research and scientific papers

Palladium-Catalyzed Sulfinylation of Aryl- And Alkenylborons with Sulfinate Esters

An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis.

Stereoselective radical Aryl migration reactions from sulfur to carbon

Stereoselective aryl migration reactions from sulfur in sulfonates and sulfonamides to C-centered radicals are reported. The 1,5-aryl migration from sulfur to differently substituted C-centered radicals could be performed with high yields and selectivities. Functionalized aryl groups could also be transferred by this new method. A model to explain the stereochemical outcome of the reaction is presented and some mechanistic aspects of this reaction are discussed. Aryl migration reactions from sulfur in sulfinates to carbon radicals were less efficient, and the corresponding migrations in aryl sulfoxides were not observed at all. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.