606129-09-3

Upstream product

• 1019753-37-7 ((1R,2S)-3-Benzenesulfonyl-2-methyl-5-phenylsulfanyl-cyclohept-4-enyloxy)-tert-butyl-dimethyl-silane 
• 1019753-91-3 C₁₄H₁₆O₃S 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 945931-77-1 C₂₀H₃₀O₄SSi 
• 906076-71-9 (1S,4R,6R,7R)-3-Benzenesulfonyl-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,5-dimethyl-pyrazol-1-yl)-7-methyl-cyclohept-2-enol 
• 906076-75-3 (4R,5S,6S,7S)-1-Benzenesulfonyl-4,6-bis-(tert-butyl-dimethyl-silanyloxy)-5,7-dimethyl-cycloheptene 
• 906076-78-6 (1R,5S,6S,7S)-6-(tert-butyldimethylsilyloxy)-5,7-dimethyl-4-(phenylsulfonyl)cyclohept-3-enol 
• 945931-90-8 C₂₁H₃₄O₄SSi 
• 906076-73-1 (1S,2S,6R,7R)-3-Benzenesulfonyl-6-(tert-butyl-dimethyl-silanyloxy)-2,7-dimethyl-cyclohept-3-enol 
• 906076-69-5 tert-butyldimethyl(((1S,2R,3R,7S)-2-methyl-6-(phenylsulfonyl)-8-oxabicyclo[5.1.0]oct-5-en-3-yl)oxy)silane 

Relevant academic research and scientific papers

Second-generation synthesis of syn- and anti-cycloheptadienylsulfone polyketide stereodiads

(Chemical Equation Presented) Stereodiad sulfones 18a and 18b are key intermediates for polyketide synthesis. This note describes the synthesis of 18a and 18b from enantiopure epoxide 2. The two sequences have been optimized for large-scale synthesis to g

Functionality propagation by alkylative oxidation of cross-conjugated cycloheptadienyl sulfones

Getting the most out of sulfur. Enantiopure epoxyvinyl sulfone 1 is transformed to syn- and anti-dienyl sulfones 2 and 3, respectively, by means of a nucleophilic methylation/sulfenylation/directed elimination reaction sequence. Compound 2 has been converted into termini-differentiated seven-carbon polypropionate segments found in five biologically significant natural products.