606133-11-3

Upstream product

• 606133-02-2 tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane 
• 606133-04-4 6-(tert-butyldiphenylsilanyloxymethyl)-hepta-2,6-dien-1-ol 
• 63082-55-3 diethyl (E)-cinnamyl malonate 
• 606133-09-9 2-(6-hydroxymethylhepta-2,6-dienyl)-2-(3-phenylallyl)-malonic acid diethyl ester 

Relevant academic research and scientific papers

Triquinanes from linear alkylidene carbenes via trimethylenemethane diyls

The intramolecular [2+3] cycloaddition reaction of the trimethylenemethane diyl generated from the intramolecular cyclopropanation reaction of alkylidene carbene produced linearly fused triquinanes regio- and stereoselectively. The current tandem cycloaddition reaction was applied to a 14-step total synthesis of hirsutene from methallyl alcohol. Copyright