60676-26-8

Basic information

• Product Name: N,N,N,4,4-pentamethyl-3-oxopentan-1-aminium iodide
• CAS NO: 60676-26-8
• Molecular Formula: C₁₀H₂₂NO*I
• Molecular Weight: 299.1923
• Mol File: 60676-26-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N,N,4,4-pentamethyl-3-oxopentan-1-aminium iodide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N,N,4,4-pentamethyl-3-oxopentan-1-aminium iodide(60676-26-8)
• EPA Substance Registry System: N,N,N,4,4-pentamethyl-3-oxopentan-1-aminium iodide(60676-26-8)

Safety Data

• Hazardous Substances Data: 60676-26-8(Hazardous Substances Data)

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 22700-73-8 1-(dimethylamino)-4,4-dimethylpentan-3-one 
• 74-88-4 methyl iodide 

Downstream Products

• 200347-23-5 1-(2-Methoxy-1-methyl-2-phenylsulfanyl-ethoxy)-4,4-dimethyl-pentan-3-one 
• 200347-24-6 1-[1-(Methoxy-phenylsulfanyl-methyl)-heptyloxy]-4,4-dimethyl-pentan-3-one 
• 200347-25-7 1-[1-(Methoxy-phenylsulfanyl-methyl)-2-methyl-propoxy]-4,4-dimethyl-pentan-3-one 
• 200347-26-8 1-[1-(Methoxy-phenylsulfanyl-methyl)-3-methyl-butoxy]-4,4-dimethyl-pentan-3-one 
• 106883-63-0 3-tert-butyl-4,5-dihydro-pyrazole-1-carboxylic acid anilide 

Relevant articles and documents

The Friedel-Crafts reaction of acid chlorides with ethene; di-addition and molecular rearrangement

Acid chlorides, complexed with excess aluminium chloride, reacted with ethene to form 3-methyl-2-buten-1-ones, i.e. rearranged di-addition products having a terminal isoprenoid skeleton, together with the usual β-chloropropanones. The latter were the sole products in the absence of excess catalyst. Acid chlorides containing a suitably situated π-system underwent intramolecular cyclization, e.g. 2-phenylcyclopropanecarbonyl chloride (10) cyclized to 3,4-benzobicyclo[3.1.0]hexan-2-one (11).