606922-64-9Relevant academic research and scientific papers
Synthesis of methoxy-substituted exocyclic (E)- and (Z)-unsaturated methyl pyranosides and a study of their reactivity towards lewis acids
Deleuze, Aurelie,Sollogoub, Matthieu,Bleriot, Yves,Marrot, Jerome,Sinay, Pierre
, p. 2678 - 2683 (2007/10/03)
The first synthesis of methoxy-substituted exocyclic (E) - and (Z)-unsaturated methyl pyranosides is reported involving the syn elimination of a selenoxide derivative as a key step. The rearrangement of these exocyclic enol ethers in the presence of TIBAL and DIBAL-H is also described. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
