606970-28-9

Upstream product

• 1826-67-1 vinyl magnesium bromide 
• 302788-33-6 3,6-di-O-benzyl-4,5-O-isopropylidene-D-xylo-aldehydo-hexos-5-ulo-2,5-furanose 
• 2018-90-8 naphthalen-2-ylmethylamine 

Downstream Products

• 664366-29-4 (2R,3R,4R,5S,6R)-4-Benzyloxy-2-benzyloxymethyl-1-naphthalen-2-ylmethyl-6-vinyl-piperidine-3,5-diol 
• 606970-31-4 Acetic acid (2R,3R,4R,5S,6R)-5-acetoxy-4-benzyloxy-2-benzyloxymethyl-6-vinyl-piperidin-3-yl ester 
• 606970-30-3 Acetic acid (2R,3R,4R,5S,6R)-5-acetoxy-4-benzyloxy-2-benzyloxymethyl-1-naphthalen-2-ylmethyl-6-vinyl-piperidin-3-yl ester 

Relevant academic research and scientific papers

2-Naphthylmethyl (NAP) as a Versatile Amino Protecting Group, Chemoselective Removal under Mild Conditions

The use of 2-naphthalenemethyl (NAP) as a versatile amino protecting group is reported. Highly efficient and chemoselective cleavage of protected tertiary amines using DDQ in CH2Cl2-MeOH (4:1) has been observed in the presence of various functionalities such as hydroxyl, acetal, alkene, ester, benzyloxy and N-benzyl groups.

General access to iminosugar C-glycoside building blocks by means of cross-metathesis: A gateway to glycoconjugate mimetics

Cross-metathesis reactions of α-1-C-allyl-1-deoxynojirimycin derivatives 7a,b and various functionalized alkenes mediated by Grubbs's catalyst 3 are reported. The reactions showed reasonable to very good yields and excellent E/Z selectivity. This methodol