60702-25-2Relevant academic research and scientific papers
Electron Transfer Mechanism in the Oxidation of Aryl 1-Methyl-1-phenylethyl Sulfides Promoted by Nonheme Iron(IV)-Oxo Complexes: The Rate of the Oxygen Rebound Process
Barbieri, Alessia,Del Giacco, Tiziana,Di Stefano, Stefano,Lanzalunga, Osvaldo,Lapi, Andrea,Mazzonna, Marco,Olivo, Giorgio
, p. 12382 - 12387 (2016)
The oxidation of aryl 1-methyl-1-phenylethyl sulfides promoted by the nonheme iron(IV)-oxo complexes [(N4Py)FeIVO]2+ and [(Bn-TPEN)FeIVO]2+ occurs by an electron transfer-oxygen rebound (ET-OT) mechanism leadi
The Mechanism of Enzymatic and Biomimetic Oxidations of Aromatic Sulfides and Sulfoxides
Baciocchi, Enrico,Lanzalunga, Osvaldo,Marconi, Francesco
, p. 9771 - 9774 (2007/10/02)
Biomimetic and enzymatic oxidations of benzyl sulfides and sulfoxides lead to products (sulfoxides or sulfones) different from those obtained with bona fide electron transfer oxidations (products of C-H and/or C-S bond cleavage), which suggests the operation of an oxygen transfer machanism.
