60727-71-1

Usage

Uses

Used in Fragrance and Flavor Industry:
(E)-1-(1-cyclododecen-1-yl)ethan-1-one is used as a key component in the manufacturing of fragrances and flavors due to its pleasant and appealing smell. Its floral and green odor adds a distinct and desirable quality to various products in this industry.
Used in Chemical Synthesis:
(E)-1-(1-cyclododecen-1-yl)ethan-1-one also serves as an intermediate in the production of various other chemicals, contributing to the development of a wide range of products across different industries.
Used as a Chemical Reagent:
(E)-1-(1-cyclododecen-1-yl)ethan-1-one is utilized as a chemical reagent in organic synthesis, playing a crucial role in the creation of new compounds and materials with specific properties and applications.

InChI:InChI=1/C14H24O/c1-13(15)14-11-9-7-5-3-2-4-6-8-10-12-14/h11H,2-10,12H2,1H3/b14-11-

Upstream product

• 830-13-7 cyclododecanone 
• 14519-31-4 1-ethynylcyclododecan-1-ol 

Downstream Products

• 28925-00-0 Cyclododecylmethylketon 

Relevant academic research and scientific papers

Total synthesis of the naturally occurring furanoid fatty acid, F5

The furanoid fatty acid F5 has been synthesized using a mercury(II) catalyzed isomerization of 2-(1,2-oxiranylcyclododecyl)-3-nonyn-2-ol.

Highly stereoselective synthesis of bicyclo[n.3.0]alkanes by titanium tetrachloride promoted [3 + 2] cycloaddition of allylsilanes and 1-acetylcycloalkenes

The titanium tetrachloride promoted reaction of allylsilanes 1 with 1-acetylcyclohexene is shown to afford the silylbicyclo[4.3.0]nonanes 9 ([3 + 2] cycloaddition products) along with the 1-acetyl-2-allylcyclohexane 4 (Hosomi-Sakurai product). Here we report that systematic variation of the substituents at the silicon atom of 1 allows suppression of the classical Hosomi Sakurai reaction in favor of the [3+2] cycloaddition. Cycloaddition of the allylsilanes 1d, 1i, and 1k with 1-acetylcycloalkenes 10, containing a 5-, 6-, 7-, 8-, or 12-membered ring, gives rise to the corresponding silylbicyclo[n.3.0]alkanes 11-13. The cycloaddition of allyltriisopropylsilane (1k) and 1-acetyl-2-methylcycloalkenes 15 provides silylbicyclo[n.3.0]alkanes 16 with two contiguous quaternary carbon centers. The stereochemistry of the silylbicyclo[n.3.0]alkanes 11a-c and 14 is unambiguously determined by X-ray analysis and 13C NMR spectroscopy.

Musk-like scents and their manufacture

New 1-acyl- and 1-hydroxymethyl-cyclododecanes and -cyclododecenes. The new 1-acyl-cyclododecenes and -cyclododecanes are obtained by a Rupe or Meyer-Schuster rearrangement, with or without subsequent hydrogenation in the presence of Ni, Pd and Pt catalysts. The 1-acyl-cyclododecenes and -cyclododecanes are valuable scents of the basic type of the sought-after macrocyclic musk scents. Furthermore, they are used for the manufacture of numerous other new 1-substituted or 1-and 2-substituted cyclododecenes and cyclododecanes having good scent characteristics.