607692-57-9Relevant academic research and scientific papers
Formation of 3-aminofuran-2-(5 H)-ones and 3-amino-1 H -pyrrole-2,5-diones by rearrangement of isoxazolidines
Iannazzo, Daniela,Carnovale, Caterina,Giofrè, Salvatore V.,Ettari, Roberta,Romeo, Giovanni,Romeo, Roberto,Lanza, Giuseppe,Chiacchio, Ugo
, p. 245 - 248 (2011/04/22)
A novel rearrangement pathway of 3-alkoxycarbonyl-4- carbamoylisoxazolidines, leading to 1H-pyrrole-2,5-diones by treatment with TBAF, is reported. DFT quantum chemical calculations support the reaction route, controlled by ring strain, which proceeds thr
