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Dichlorobis(tri-p-tolylphosphine)palladium(II) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

60802-43-9

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60802-43-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 60802-43-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,0,8,0 and 2 respectively; the second part has 2 digits, 4 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 60802-43:
(7*6)+(6*0)+(5*8)+(4*0)+(3*2)+(2*4)+(1*3)=99
99 % 10 = 9
So 60802-43-9 is a valid CAS Registry Number.

60802-43-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name PdCl2 tris(p-tolyl)phosphine

1.2 Other means of identification

Product number -
Other names PdCl2(P(p-MeC6H4)3)2

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:60802-43-9 SDS

60802-43-9Relevant academic research and scientific papers

Phenoxide-assisted P-C bond cleavage in PdCl2(PPh 3)2 under very mild conditions

Yasuda, Hiroyuki,Maki, Noriko,Choi, Jun-Chul,Abla, Mahmut,Sakakura, Toshiyasu

, p. 1307 - 1310 (2006)

PdCl2(PPh3)2 reacted with NaOAr (Ar = Ph, p-tolyl) at 0 °C to afford PdCl(Ph)(PPh3)2, instead of PdCl(OAr)(PPh3)2, in 12-16% isolated yields based on Pd. The structure was confirmed by NMR and X-ray crystallography. GC-MS analysis of the reaction solution revealed that OPPh2(OAr), OPPh(OAr) 2, and OP(OAr)3 are formed, while NMR studies indicated that PdCl(Ph)(PPh3)2 is produced when PdCl(OAr)(PPh 3)2 decomposes. The reaction of PdCl2(PPh 3)2 with Bu3Sn(OC6H 4-p-OMe) also gave PdCl(Ph)(PPh3)2 in 8% isolated yield. These results suggest that PdCl(OAr)(PPh3) 2 is highly labile and the aryloxy ligand exchanges with the phenyl groups in triphenylphosphine even under very mild conditions.

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