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Tris[(trifluoromethyl)sulfonyl]methane, also known as TFMSM or TMS, is a colorless, volatile liquid chemical compound with the formula CF3SO2CH2SO2CF3. It is characterized by its high thermal stability, low toxicity, and non-flammability, which contribute to its versatility and safety in various industrial applications. TFMSM is recognized as a potent electrophilic trifluoromethylating agent and has been considered for use in lithium-ion batteries as an electrolyte additive, showcasing its unique combination of properties that make it valuable across a wide range of industries.

60805-12-1

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60805-12-1 Usage

Uses

Used in Chemical Synthesis:
Tris[(trifluoromethyl)sulfonyl]methane is used as a reagent in chemical synthesis processes for its ability to act as a powerful electrophilic trifluoromethylating agent. This property is crucial for the production of a variety of trifluoromethylated compounds, which are important in pharmaceuticals, agrochemicals, and materials science due to the unique characteristics imparted by the trifluoromethyl group.
Used in Solvent Applications:
As a solvent, Tris[(trifluoromethyl)sulfonyl]methane is utilized in various chemical processes where its volatility and stability are advantageous. Its low toxicity and non-flammability make it a safer alternative to traditional solvents, reducing the risk of environmental and health hazards associated with more hazardous solvents.
Used in Lithium-Ion Battery Technology:
Tris[(trifluoromethyl)sulfonyl]methane is studied for its potential use as an electrolyte additive in lithium-ion batteries. Its unique properties may enhance the performance and safety of these batteries, which are critical for applications in portable electronics, electric vehicles, and renewable energy storage systems.
Used in Industrial Processes:
Due to its thermal stability and other properties, Tris[(trifluoromethyl)sulfonyl]methane is employed in a range of industrial processes where high-temperature resistance and chemical reactivity are required. This includes applications in the production of specialty chemicals, materials, and intermediates that demand robust and reliable performance under demanding conditions.

Check Digit Verification of cas no

The CAS Registry Mumber 60805-12-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,0,8,0 and 5 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 60805-12:
(7*6)+(6*0)+(5*8)+(4*0)+(3*5)+(2*1)+(1*2)=101
101 % 10 = 1
So 60805-12-1 is a valid CAS Registry Number.

60805-12-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name bis(trifluoromethylsulfonyl)methylsulfonyl-trifluoromethane

1.2 Other means of identification

Product number -
Other names TRIS[(TRIFLUOROMETHYL)SULFONYL]METHANE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:60805-12-1 SDS

60805-12-1Relevant academic research and scientific papers

Taming the Lewis Superacidity of Non-Planar Boranes: C?H Bond Activation and Non-Classical Binding Modes at Boron

Berionni, Guillaume,Champagne, Beno?t,Chardon, Aurélien,Fusaro, Luca,Mahaut, Damien,Osi, Arnaud,Tumanov, Nikolay,Wouters, Johan

supporting information, (2022/01/20)

The rational design of a geometrically constrained boron Lewis superacid featuring exceptional structure and reactivity is disclosed. It enabled the formation of non-classical electron deficient B?H?B type of bonding, which was supported by spectroscopic and structural parameters as well as computational studies. Taming the pyramidal Lewis acid electrophilicity through weak coordinating anion dissociation enabled a series of highly challenging chemical transformations, such as Csp2?H and Csp3?H activation under a frustrated Lewis pair regime and the cleavage of Csp3?Si bonds. The demonstration of such rich chemical behaviour and flexibility on a single molecular compound makes it a unique mediator of chemical transformations generally restricted to transition metals.

METHOD FOR PRODUCING TRIS(PERFLUOROALKANESULFONYL)METHIDE ACID SALT

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Page/Page column 7, (2009/08/14)

There is provided a method for producing a tris(perfluoroalkanesulfonyl)methide acid salt represented by formula [1], including the steps of (a) reacting a methylmagnesium halide represented by formula [2] with a perfluoroalkanesulfonyl fluoride represented by formula [3], thereby obtaining a reaction mixture; and (b) directly reacting the obtained reaction mixture with at least one selected from the group consisting of alkali metal halides, quaternary ammonium salts, and quaternary phosphonium salts. By this method, it is possible to easily produce the target methide acid salt with high yield.

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