608528-63-8Relevant academic research and scientific papers
Enyne Metathesis: A Catalytic, Cross-Selective Diene Synthesis
Diver, Steven T.,Giessert, Anthony J.
, p. 466 - 471 (2004)
Methods for the synthesis of 1,3-dienes by intermolecular enyne metathesis are described. A brief overview of enyne metathesis is provided with a discussion of the scope and limitations with respect to reactants and catalyst. The surge of recent interest in metathesis generally and the cross enyne metathesis specifically, has closely matched the development of the functional group-tolerant Grubbs' carbene catalysts.
Cycloheptadiene Ring Synthesis by Tandem Intermolecular Enyne Metathesis
Kulkarni, Amol A.,Diver, Steven T.
, p. 3463 - 3466 (2007/10/03)
(Equation presented) The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene r
