608530-06-9Relevant academic research and scientific papers
Indium-mediated alkynylation in C-glycoside synthesis
Picard, Julien,Lubin-Germain, Nadege,Uziel, Jacques,Auge, Jacques
, p. 979 - 982 (2006)
The indium-mediated alkynylation of perbenzylated or peracetylated formylglucose is a pathway for the synthesis of various C-glycosides. Hydroxylated, ketonic, mono- or difluorinated, and methylated C-glycosides were thus obtained. Georg Thieme Verlag Stu
New aspects in the stereoselective ethynylation of β-C-glycoside aldehydes. Application to the synthesis of an ambruticin fragment
Michelet, Veronique,Adiey, Kouacou,Tanier, Suzelle,Dujardin, Gilles,Genet, Jean-Pierre
, p. 2947 - 2958 (2007/10/03)
Stereoselective ethynylation of functionalized β-C-glycosyl aldehydes has been achieved with various organometallic alkynes, The diastereoselectivity is highly dependent on the organometallic alkyne and on the functionalization on the C-6 position of the
