608530-10-5

Upstream product

• 2937-50-0 Allyl chloroformate 
• 608529-93-7 (1R,4R)-1-(2,3,4,6-tetra-O-benzyl-D-gluco-β-C-pyranosyl)-4-O-(tert-butyldimethylsilyl)pent-2-yne-1,4-diol 

Downstream Products

• 608530-11-6 (1R,4R)-1-O-allyloxycarbonyl-1-(2,3,4,6-tetra-O-benzyl-D-gluco-β-C-pyranosyl)pent-2-yne-1,4-diol 
• 608529-97-1 (1R,4R)-1-(2,3,4,6-tetra-O-benzyl-D-gluco-β-C-pyranosyl)-4-O-(ethoxycarbonyl)pent-2-yne-1,4-diol 
• 608530-13-8 (1R,2Z,4R)-1-(2,3,4,6-tetra-O-benzyl-D-gluco-β-C-pyranosyl)-4-O-(ethoxycarbonyl)pent-2-ene-1,4-diol 
• 608529-98-2 methyl (3S,4E,6R)-6-(2,3,4,6-tetra-O-benzyl-D-gluco-β-C-pyranosyl)-6-hydroxy-2-(methoxycarbonyl)-3-methylhex-4-enoate 
• 608530-12-7 (1R,4R)-1-O-allyloxycarbonyl-1-(2,3,4,6-tetra-O-benzyl-D-gluco-β-C-pyranosyl)-4-O-(ethoxycarbonyl)pent-2-yne-1,4-diol 
• 608530-14-9 methyl (3S,4E,6R)-6-(2,3,4,6-tetra-O-benzyl-D-gluco-β-C-pyranosyl)-6-(2,4-dichlorobenzoyloxy)-2-(methoxycarbonyl)-3-methylhex-4-enoate 

Relevant academic research and scientific papers

New aspects in the stereoselective ethynylation of β-C-glycoside aldehydes. Application to the synthesis of an ambruticin fragment

Stereoselective ethynylation of functionalized β-C-glycosyl aldehydes has been achieved with various organometallic alkynes, The diastereoselectivity is highly dependent on the organometallic alkyne and on the functionalization on the C-6 position of the