6087-87-2

Usage

General Description

2H-1-Benzothiopyran, 3,4-dihydro-2-methyl- is a chemical compound that belongs to the family of benzothiopyrans, which are heterocyclic compounds containing a benzene ring fused to a thiophene ring. It is also known as 2-Methyl-3,4-dihydro-1-benzothiopyran and has the molecular formula C10H10S. 2H-1-Benzothiopyran, 3,4-dihydro-2-methyl- is a colorless to pale yellow liquid at room temperature and is commonly used in the synthesis of organic compounds. It is also known to possess various biological activities and is under research for its potential pharmaceutical applications.

Upstream product

• 123-73-9 trans-Crotonaldehyde 
• 108-98-5 thiophenol 
• 702-04-5 crotyl phenyl sulfide 

Relevant academic research and scientific papers

Improve method for synthesis of 4-thioaryl-2,3,4-trihydro-1-benzo-thiopyrans: Acid-induced stereoselective intermolecular cycloaddition of α,β-unsaturated aldehydes with arenethiols

A catalytic amount of acids catalyzed reaction of α,β-unsaturated aldehydes with arenethiols in 1,2-dichloroethane brought about intermolecular cycloaddition to give the corresponding 4-thioaryl-2,3,4-trihydro-1-benzothiopyrans (thiochromans) in good to e

MECHANISM OF THE THIO-CLAISEN REARRANGEMENT OF 3-METHYLALLYL PHENYL SULFIDE

The thio-Claisen rearrangement of isomeric 3- and 1-methylallyl phenyl sulfides was investigated.It is demonstrated that the thio-Claisen rearrangement of the 3-methyl isomer is preceded by its thioallyl rearrangement to the 1-methyl isomer.The latter undergoes thio-Claisen rearrangement to o-(3-methylallyl)thiophenol, which is cyclized to 2-ethyl-2,3-dihydrobenzothiophene and 2-methylthiochroman under the reaction conditions.