60887-91-4Relevant academic research and scientific papers
Novel Rearrangement of 5,6-Disubstituted Bicyclooctan-2-ones with AlCl3. Application to Total Synthesis of (+/-)-5-Oxosilphiperfol-6-ene and (+/-)-Silphiperfol-6-ene
Kakiuchi, Kiyomi,Ue, Masaki,Tsukahara, Hiroshi,Shimizu, Toshihiro,Miyao, Tomoya,et al.
, p. 3707 - 3712 (2007/10/02)
The acid-catalyzed rearrangement of bi- and tricyclic cyclobutyl ketones 8-20 having a bicyclooctan-2-one moiety with AlCl3 was studied to elucidate the scope and limitations of the novel rearrangement by which the tricyclic ketone 1 gave the angul
Reductive Rearrangement with Hydride Transfer of Linearly and Angularly Fused Triquinanes
Kakiuchi, Kiyomi,Ue, Masaki,Kumanoya, Shuichi,Takeuchi, Hideyuki,Tobe, Yoshito,Odaira, Yoshinobu
, p. 1479 - 1482 (2007/10/02)
Relationship between linearly and angularly fused triquinanes is elucidated by reductive rearrangements with hydride transfer of tricyclo2,6>undecan-1-ol, tricyclo1,5>undecan-6-ols, and tricyclo1,5>undecan-11-ol.
Acid-Catalyzed Rearrangements of - and Propellanes, Tricyclo1,5>undecanes, and Tricyclo1,5>undecanes
Kakiuchi, Kiyomi,Ue, Masaki,Wakaki, Itsuyo,Tobe, Yoshito,Odaira, Yoshinobu,et al.
, p. 281 - 287 (2007/10/02)
Acid-catalyzed rearrangements of propellanols 2x and 2n, propellanol (3b), tricyclo1,5>-undecanes 4b-d and 5, and tricyclo1,5>undecanes 6a,b were studied.Tricycloundecanes 4d and 6b rearranged under CF3S
ACID CATALYZED RING CONTRACTIONS IN ENDO-2,8-TRIMETHYLENE-CIS-BICYCLOOCTYL CATIONS TO METHYLPERHYDROTRIQUINACENES. ONE OF THE METHYL EXTRUSION PROCESSES IN THE TRICYCLOUNDECANE REARRANGEMENT
Fujikura, Yoshiaki,Takaishi, Naotake,Inamoto, Yoshiaki
, p. 4465 - 4478 (2007/10/02)
Sulfuric acid catalyzed ring contractions with extrusion of a methyl group were examined for alcohol and olefin derivatives (28-31) of endo-2,8-trimethylene-cis-bicyclooctane (11), which was one of the two possible progenitors, among altogether 69
