609769-99-5

Basic information

• Product Name: Benzenamine, N-(diphenyl-2-pyridinylphosphoranylidene)-2,6-dimethyl-
• CAS NO: 609769-99-5
• Molecular Formula: C25H23N2P
• Molecular Weight: 382.445
• Mol File: 609769-99-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(diphenyl-2-pyridinylphosphoranylidene)-2,6-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(diphenyl-2-pyridinylphosphoranylidene)-2,6-dimethyl-(609769-99-5)
• EPA Substance Registry System: Benzenamine, N-(diphenyl-2-pyridinylphosphoranylidene)-2,6-dimethyl-(609769-99-5)

Safety Data

• Hazardous Substances Data: 609769-99-5(Hazardous Substances Data)

Upstream product

• 37943-90-1 2-(diphenylphosphino)pyridine 
• 26334-20-3 2,6-dimethylphenylazide 

Downstream Products

• 677021-94-2 (C₆H₅)2(C₅H₄N)PN(C₆H₃(CH₃)2)Pd(CH₃)(NCCH₃)⁽¹⁺⁾*BF₄^(1-)=[(C₆H₅)2(C₅H₄N)PN(C₆H₃(CH₃)2)Pd(CH₃)(NCCH₃)]BF₄ 
• 609770-23-2 (2-(2,6-Me₂C₆H₃NPPh₂)C₅H₄N)FeCl₂ 
• 677021-91-9 (C₆H₅)2(C₅H₄N)PN(C₆H₃(CH₃)2)PdCl(CH₃) 
• 609770-11-8 (2-(2,6-Me₂C₆H₃NPPh₂)C₅H₄N)NiBr₂*CH₂Cl₂ 

Relevant articles and documents

Palladium(II) complexes containing a pyridinyliminophosphorane ligand

A series of new pyridinyliminophosphorane bidentate ligands with different steric environments [(2-C6H4N)PPh2= NAr (NPN)] and their methylpalladium complexes PdClMe(NPN)] were prepared. From the crystal structure analysis it is evident that the alkyl ligands are always trans to the pyridinyl nitrogen donor, revealing a σ-donating ability of the iminophosphorane. However, the two Pd-Cl bonds in [PdCl2(NPN)] are essentially the same length. Cationic palladium complexes catalyzed the copolymerization of norbornene/ethylene as well as CO/norbornene. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.