609817-39-2

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 609817-40-5 (Z)-(2S,3R,4S,10S)-4-Azido-3-[(R)-4-benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-butyl]-11-methoxymethoxy-2,10-dimethyl-undec-7-en-1-ol 
• 112763-39-0 (3S)-4-(methoxymethoxy)-3-methylbutanal 
• 609817-38-1 Methanesulfonic acid (Z)-(1R,7S)-1-{(1S,2R)-5-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-pentyl}-8-methoxymethoxy-7-methyl-oct-4-enyl ester 
• 609817-36-9 (Z)-(4R,5R,12S)-1-benzyloxy-4-(tert-butyldimethylsilanyloxy)-5-[(S)-2-(tert-butyldimethylsilanyloxy)-1-methylethyl]-13-methoxymethoxy-12-methyltridec-9-en-6-one 
• 609817-32-5 tert-Butyl-((Z)-(S)-7-methoxymethoxy-6-methyl-hept-3-enyloxy)-dimethyl-silane 
• 609817-34-7 C₁₀H₁₉LiO₂ 
• 609817-29-0 (2S)-7-iodo-1-(methoxymethoxy)-2-methyl-4-heptene 
• 112763-37-8 (2R)-1-(methoxymethoxy)-2-methyl-3-(p-tolylsulfonyloxy)propane 

Downstream Products

• 27498-90-4 stemonine 
• 609817-41-6 (Z)-(2S,8S,9R,10R)-8-azido-13-benzyloxy-10-(tert-butyldimethylsilanyloxy)-9-[(S)-2-(tert-butyldimethylsilanyloxy)-1-methylethyl]-2-methyltridec-4-enoic acid methyl ester 
• 1026570-35-3 (Z)-(2S,8S,9R,10R)-8-Azido-13-benzyloxy-10-(tert-butyl-dimethyl-silanyloxy)-9-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-2-methyl-tridec-4-enoic acid 
• 609817-45-0 (Z)-(2S,8S,9R,10R)-8-Azido-13-benzyloxy-10-(tert-butyl-dimethyl-silanyloxy)-9-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-2-methyl-tridec-4-en-1-ol 

Relevant academic research and scientific papers

Total synthesis of (-)-stemonine

(Matrix Presented) An enantioselective total synthesis of (-)-stemonine (1) is reported via a convergent assembly of the acyclic precursor 2. Key transformations include a Staudinger-aza-Wittig reaction to form the central perhydroazepine ring system and