6099-21-4

Basic information

• Product Name: 1,2-Bis(phenylsulfinyl)ethane
• Synonyms: 1,2-Bis(phenylsulfinyl)ethane;1,2-Bis(phenylsulfinyl)ethane,98%
• CAS NO: 6099-21-4
• Molecular Formula: C₁₄H₁₄O₂S₂
• Molecular Weight: 278.39
• Product Categories: organosulfur compound
• Mol File: 6099-21-4.mol
• Article Data: 11

Chemical Properties

• Melting Point: 160 °C
• Boiling Point: 70 °C(Press: 0.25 Torr)
• Appearance: white to off-white/Powder
• Density: 1.36±0.1 g/cm3(Predicted)
• Storage Temp.: Sealed in dry,Room Temperature
• Stability: store cold
• CAS DataBase Reference: 1,2-Bis(phenylsulfinyl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Bis(phenylsulfinyl)ethane(6099-21-4)
• EPA Substance Registry System: 1,2-Bis(phenylsulfinyl)ethane(6099-21-4)

Safety Data

• Hazardous Substances Data: 6099-21-4(Hazardous Substances Data)

Usage

General Description

1,2-Bis(phenylsulfinyl)ethane is an organic compound with the molecular formula C14H14O2S2. It is a sulfoxide, which is a type of organosulfur compound. This chemical is used as a chiral ligand in asymmetric synthesis and as a chiral auxiliary in various organic reactions. It has been found to be effective in catalyzing a variety of reactions, particularly in the formation of carbon-carbon and carbon-nitrogen bonds. 1,2-Bis(phenylsulfinyl)ethane has also been studied for its potential pharmaceutical applications, due to its unique stereochemical properties and ability to influence the stereochemistry of reactions. Overall, this chemical has shown promise as a versatile and important reagent in organic synthesis.

Upstream product

• 31268-20-9 bromomethyl phenyl sulfoxide 
• 622-20-8 1,2-bis(phenylthio)ethane 
• 107-21-1 ethylene glycol 
• 931-59-9 benzenesulfenyl chloride 
• 3111-52-2 potassium thiophenolate 
• 7722-84-1 dihydrogen peroxide 
• 20451-53-0 Phenyl vinyl sulfoxide 
• 13456-86-5 3,5-Dichloro-2,4,6-trimethyl-benzonitrile N-oxide 
• 87330-63-0 1,1,2,2-tetramethyl-1,2-disilacyclohexa-3,5-diene 
• 108-98-5 thiophenol 

Downstream Products

• 622-20-8 1,2-bis(phenylthio)ethane 
• 21461-90-5 (meso)-1,2-bis(phenylsulfinyl)ethane 
• 1403825-13-7 Pd(1,2-bis(phenylsulfinyl)ethane)(trifluoroacetate)₂ 

Relevant articles and documents

Thermodynamic Resolution and Enantioselective Synthesis of C2-Symmetric Bis-sulfoxides Based on Chiral Iridium(III) Complexes

Enantiopure λ-[Ir(dfppy)2(MeCN)2](PF6) and Δ-[Ir(dfppy)2(MeCN)2](PF6) (where dfppy is (4,6-difluoropheny)pyridine) were demonstrated to preferentially react with (S,S)-1,2-bis(arylsulfinyl)

Metal- and additive-free oxygen-atom transfer reaction: an efficient and chemoselective oxidation of sulfides to sulfoxides with cyclic diacyl peroxides

Metal- and additive-free oxidation of a series of sulfides/thioketones has been achieved using cyclic diacyl peroxides as mild oxygen sources. This protocol features simple manipulation, high chemo- and diastereoselectivity, and a broad substrate scope (up to 42 examples), tolerates many common functional groups, and is scalable and applicable to the late-stage sulfoxidation strategy. A preliminary mechanistic study by quantum mechanical calculations suggests that a single two-electron transfer process is energetically more favorable, and indicates the reactivity of cyclic diacyl peroxides distinct from conventional acyclic acyl peroxides.

Catalytic intermolecular allylic C-H alkylation

The first electrophilic Pd(II)-catalyzed allylic C-H alkylation is reported, providing a novel method for formation of sp3-sp3 C-C bonds directly from C-H bonds. A wide range of aromatic and heteroaromatic linear (E)-α-nitro-arylpent