61008-72-8

Upstream product

• 20672-66-6 3,4,6-tri-O-benzyl-D-glucopyranose 
• 38081-38-8 3,4,6-tri-O-acetyl-1,2-O-<1-(exo-ethoxy)ethylidene>-α-D-glucopyranose 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 158852-31-4 3,4,6-tri-O-benzyl-1,2-O-(exo-ethoxyethylidene)-α-D-glucopyranose 

Downstream Products

• 205693-51-2 2-Benzyloxy-6-{(R)-16-[(2R,3S,4S,5R)-3,4,6-tris-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2-(3,4-dimethoxy-benzyloxy)-hexanoyloxy]-heptadecyl}-benzoic acid benzyl ester 
• 205693-53-4 2-Benzyloxy-6-{(R)-16-[(2R,3S,4S,5R)-3,4,6-tris-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2-trifluoromethanesulfonyloxy-hexanoyloxy]-heptadecyl}-benzoic acid benzyl ester 
• 205693-54-5 2-benzyloxy-6-{(16R)-[2-O-acetyl-3,4,6-tri-O-benzyl-5-O-tert-butyldimethylsilyl-D-mannonoyloxy]heptadecyl}benzoic acid benzyl ester 
• 205693-52-3 2-benzyloxy-6-{(16R)-[3,4,6-tri-O-benzyl-5-O-tert-butyldimethylsilyl-D-gluconoyloxy]heptadecyl}benzoic acid benzyl ester 
• 205693-55-6 2-benzyloxy-6-{(16R)-[2-O-acetyl-3,4,6-tri-O-benzyl-D-mannonoyloxy]heptadecyl}benzoic acid benzyl ester 
• 205693-49-8 3,4,6-tri-O-benzyl-2-O-(3,4-dimethoxybenzyl)-5-O-tert-butyldimethylsilyl-D-gluconic acid 
• 1054659-87-8 (2R,3S,4S,5R)-3,4,6-Tris-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2-(3,4-dimethoxy-benzyloxy)-hexanoyl chloride 
• 205693-47-6 3,4,6-tri-O-benzyl-2-O-(3,4-dimethoxybenzyl)-5-O-tert-butyldimethylsilyl-D-glucitol 
• 205693-46-5 3,4,6-tri-O-benzyl-1,2-O-(3,4-dimethoxybenzylidene)-5-O-tert-butyldimethylsilyl-D-glucitol 
• 205693-45-4 3,4,6-tri-O-benzyl-1,2-O-(3,4-dimethoxybenzylidene)-D-glucitol 

Relevant academic research and scientific papers

Total synthesis of caloporoside

The first total synthesis of the fungal metabolite caloporoside 1, a strong and selective inhibitor of phospholipase C, is described. Both sugar units of its complex disaccharidic segment were obtained from 3,4,6-tri-O- benzyl-D-glucopyranose 14 as a comm

Synthesis of benzyl and allyl ethers of D-glucopyranose

Starting from allyl 3-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside as a key intermediate, the following crystalline compounds were prepared: 2-O-allyl-3,4,6-tri-O-benzyl-D-glucopyranose (11) and its p-nitrobenzoate; 2,3,5-tri-O-benzyl-D-arabinofuranose (12) and the corresponding arabinitol; allyl 3,4,6-tri-O-benzyl-α-D-glucopyranoside (7); 3,4,6-tri-O-benzyl-D-glucopyranose (8); 2-O-allyl-3,4-di-O-benzyl-D-glucopyranose (17) and its bis(p-nitrobenzoate); and 3,4-di-O-benzyl-D-glucopyranose (19). The p-nitrobenzoates of compounds 11 and 17 are potential intermediates for the synthesis of the glycolipids of the cytoplasmic membranes of Streptococci.