61047-43-6Relevant articles and documents
A Ni0 σ-Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization
Nozaki, Kyoko,Seidel, Falk William
supporting information, (2021/12/23)
While of interest, synthetically feasible access to boryl ligands and complexes remains limited, meaning such complexes remain underexploited in catalysis. For bidentate boryl ligands, oxidative addition of boranes to low-valent IrI or Pt0 are the only examples yet reported. As part of our interest in developing improved group 10 ethylene polymerization catalysts, we present here an optimized synthesis of a novel, rigid borane/phosphine ligand and its Ni0 σ-borane complex. From the latter, an unprecedented oxidative dehydrochloroborylation, to give a NiII boryl complex, was achieved. Furthermore, this new B/P ligand allowed the nickel-catalyzed polymerization of ethylene, which suggests that Ni0 σ-hydroborane complexes act as masked NiII boryl hydride reagents.
Preparation method and application of thioimino quinoline metal compound
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Paragraph 0017-0018, (2021/11/21)
The invention relates to a preparation method of a thioimino quinoline chromium metal compound and application of the thioimino quinoline chromium metal compound in olefin polymerization. According to the invention, a quinoline skeleton is introduced, a novel metal compound of thioimino quinoline chromium is designed and synthesized, and the space effect and the electronic effect of the metal catalyst with the structure can be conveniently regulated and controlled by changing the substituent group of the ligand, so that different catalytic properties are realized. The novel metal compound of thioimino quinoline chromium reported by the invention has the characteristics of cheap and easily available raw materials, simple synthetic route and high product yield, and in the presence of MAO, all chromium complexes show medium to high activity to ethylene polymerization, and the activity is up to 9.17 * 10 g.mol (Cr). h. Therefore, the novel metal compound of thioimino quinoline chromium reported by the invention has original innovation, and can enhance the competitive power of the polyolefin high polymer material technology market in China.
Chiral Memory in Silyl-Pyridinium and Quinolinium Cations
Fernandes, Anthony,Laye, Claire,Pramanik, Suman,Palmeira, Dayvson,Pekel, ?zgen ?mür,Massip, Stéphane,Schmidtmann, Marc,Müller, Thomas,Robert, Frédéric,Landais, Yannick
supporting information, p. 564 - 572 (2020/01/09)
Pyridine- and quinoline-stabilized silyl cations have been prepared, and their structure in condensed phases unambiguously assigned using 1H, 13C, 15N, 29Si, and 1H DOSY NMR as well as X-ray diffraction studies. Solid state structures thus show in both cases a stabilization of the cationic silicon center through an N-Si interaction and formation of a highly strained four-membered ring system. Chiral memory at the silicon atom in these heterocycle-stabilized silyl cations was also established, leading to various levels of selectivity depending on the nature of the heterocycle. Lowest energy conformations of the starting silanes obtained through DFT calculations, along with the isolation and characterization of the Si-centered chiral silyl cation intermediates, finally allowed to propose a plausible hypothesis as to the configurational stability of these silyl cations.